Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Heteroatomic Rings

The preparation of the symmetrical eight-membered ring cyclo-l,2,5,6-Se4S4 (12.5) involves a further elaboration of the method [eqn (12.3)]. These syntheses are typically conducted at room temperature in CS2. [Pg.280]


Heteroatom rings, such as that found in quinoline derivatives, can be generated from amino-ketones with [hydroxy(tosyloxy)iodo]benzene and perchloric acid. Cyclic imines are converted to pyridine derivatives with NCS and then excess sodium methoxide. ... [Pg.1511]

Allcock HR (1967) Heteroatom ring systems and polymers. Academic, New York... [Pg.229]

Allcock, H. R. Heteroatom Ring Systems and Polymers Academic Press New York, 1967. [Pg.204]

Computations performed on an N-methylated imidazole showed that the presence of the methyl group increases the proton affinity of the other nitrogen. In contrast, a peptide substituent at a carbon adjacent to the nitrogen decreases its proton affinity. This can be explained by the conjugation stabilization of the peptide-substituted neutral form, which is absent in the protonated form. This result seems to indicate that heteroatomic rings linked by... [Pg.171]

Reactions of Substituents Attached to Ring Carbon Reactions of Substituents Attached to Ring Heteroatoms Ring Synthesis... [Pg.567]

Cotton effects due to unsymmetrical heteroatom ring-substituted cyclohexanones have also been recorded34. However, direct application of the octant rule to determine the absolute configuration of heterocyclohexanones such as 8 is not recommended30. [Pg.502]

H. R. Allcock, Heteroatom Ring Structure Polymers, Academic Press, New York (1967). [Pg.184]

NMR spectroscopy ( Se, /= 1/2, 7%) is a powerful technique for identifying cyclic selenium molecules, especially the heteroatomic ring systems that contain sulfur or tellurium in addition to selenium, for which several isomers are possible for most compositions (Section 12.1.2). Solutions of monoclinic selenium in CS2 have been shown by high-performance liquid chromatography to form an equilibrium mixture of cyclo-Seg, cyclo-Sey and cyclo-Se6. The Se NMR spectra of such solutions show two singlets that are attributable to cyclo-Seg and cyclo-Se with relative intensities that correspond to a molar ratio of ca 6 No resonance is observed for cyclo-Sey presumably as a result of the fluxional behaviour (pseudorotation) of the seven-membered ring (Section 12.1.2). [Pg.278]

The four Problems are arranged in increasing order of difficulty. They involve several common functional groups, a highly substituted aromatic ring, a substituted heteroatom ring with a chiral center, and a diunsatur-ated terpenol. Extensive use is made of 2-D spectra. [Pg.122]

There are a number of reactions related to the photo-Fries process, in which cleavage of a bond adjacent to a heteroatom ring substituent leads by way of radical intermediates to a ring-substituted product. As an illustration, N-phenylcaprolactam, which can be regarded as... [Pg.85]

Fused Rings and Polymers. Borazine analogues of naphthalene and substituted phenalenes are known the latter compound is formed by reaction of distannylamine and a large excess of tris(methylthio)borane (137). A general method for the preparation of the polycyclic borazines using fused carbon—heteroatom rings, where X = O, NR and n = 2,3, has been given (137). [Pg.267]

Tandem mass spectrometry is also developing into an important analytical method for application to coal-derived materials (Wood, 1987). The analysis of heteroatom ring species and hydrocarbon species in coal-derived liquids offers indications of the location of the heteroatoms in, or on, ring systems, as well as indications of the hydrocarbon systems. [Pg.175]

S- and 0-compounds, saturation of the N- and O-heteroatom ring was necessary prior to hydrodenitrogenation, HDN, but that this was not the case for S-compounds. This work suggests that the reaction network obtained for a model nitrogen compound will be the one that would occur in complex mixtures such as coal liquids.(7)... [Pg.315]


See other pages where Heteroatomic Rings is mentioned: [Pg.140]    [Pg.267]    [Pg.2]    [Pg.265]    [Pg.274]    [Pg.171]    [Pg.234]    [Pg.234]    [Pg.115]    [Pg.279]    [Pg.140]    [Pg.689]    [Pg.2]    [Pg.478]    [Pg.272]    [Pg.547]    [Pg.31]    [Pg.291]    [Pg.37]    [Pg.439]    [Pg.815]    [Pg.817]    [Pg.828]    [Pg.830]    [Pg.246]    [Pg.445]    [Pg.156]   


SEARCH



3- Membered rings three heteroatoms

4- Membered rings with three heteroatoms

5-Membered rings heteroatoms

APPLICATIONS OF THREE-MEMBERED RINGS WITH TWO HETEROATOMS

Aromatic ring heteroatom

BICYCLIC ANALOGUES WITH MORE THAN TWO RING-HETEROATOMS

Benzene ring heteroatoms introduced into

Bicyclic 5-5 and 5-6 Ring Systems with Three Heteroatoms

CHARACTERISTICS OF HETEROATOMS IN RINGS

Carbon-Heteroatom Bond Formation by Rh-Catalyzed Ring-Opening Reactions

Compounds with Heteroatom Five-membered Ring Ligands

Directing effects of the ring heteroatom

ELECTROPHILIC ATTACK ON RING HETEROATOMS

Effects of a Polar Substituent and Heteroatoms in the Ring

Eight-membered Rings containing One Heteroatom

Eight-membered Rings containing Three or More Heteroatoms

Eight-membered Rings containing Two Heteroatoms

Five-Membered Ring Systems with Two or More Heteroatoms

Five-Membered Rings One Heteroatom

Five-Membered Rings with More Than Two Heteroatoms

Five-Membered Rings with Two Heteroatoms

Five-membered ring systems heteroatoms

Five-membered rings heteroatoms

Heteroaromatic radicals, Part 1, general ring heteroatoms

Heteroaromatic radicals, Part I, general ring heteroatoms

Heteroatom Ring Systems

Heteroatoms in Each Ring

Heteroatoms, three-membered ring opening with

Heterocyclic compounds four heteroatomic rings

Heterocyclic compounds three heteroatomic rings

In computing heteroatom-rich five- and sixmembered ring systems

More Than One Heteroatom in the Five-Membered Ring

NUCLEOPHILIC ATTACK ON RING HETEROATOMS

Nuclear magnetic resonance 5- membered rings, one heteroatom

Of heterocycles: five-membered rings with one heteroatom

Of heterocycles: five-membered rings with two or more heteroatoms

One Heteroatom Adjacent to the Ring Junction

One Heteroatom at a Ring Junction

One Heteroatom in Each Ring

Orientation in azole rings containing three or four heteroatoms

Other Heteroatoms in the Ring

REACTIVITY OF THREE-MEMBERED RINGS WITH TWO HETEROATOMS

Reactions with Five-Membered Ring Systems Containing One Heteroatom

Reactivity of Five-membered Rings with One Heteroatom

Reactivity of Five-membered Rings with Two or More Heteroatoms

Reactivity of Substituents Attached to Ring Heteroatoms

Ring expansion heteroatoms

Ring formation four-heteroatomic rings

Ring formation three-heteroatomic rings

Ring structure heteroatoms

Ring with heteroatom nucleophiles

Ring-Opening Unsymmetrical Oxa- and Aza-bicyclic Alkenes with Heteroatom Nucleophiles

Ring-Opening of Vinyl Epoxides with Heteroatom Nucleophiles

Ring-heteroatom backbone structure

Rings Containing Three Heteroatoms The Triazines

Rings With More Than One Heteroatom

Rings containing More than One Heteroatom

Rings containing One Heteroatom

Rings containing Two Heteroatoms

Rings that Contain One Heteroatom

Rings that Contain Three or More Heteroatoms

STRUCTURE OF THREE-MEMBERED RINGS WITH TWO HETEROATOMS

SYNTHESIS OF THREE-MEMBERED RINGS WITH TWO HETEROATOMS

Saturated Six-Membered Rings with Two Heteroatoms

Saturated bicyclic 6/5 ring-fused systems additional heteroatom

Saturated bicyclic 6/5 ring-fused systems with additional heteroatom

Saturated bicyclic 6/5 ring-fused systems with heteroatom

Seven-membered Rings containing Three or More Heteroatoms

Seven-membered rings three heteroatoms

Six-Membered Rings with Three Heteroatoms

Six-Membered Rings with Two Heteroatoms

Steroids with a Heteroatom in Ring

Structure of Five-membered Rings with One Heteroatom

Structure of Five-membered Rings with Two or More Heteroatoms

Sulfur compounds heteroatoms, five-membered rings

Synthesis of Five-Membered Rings with Two Heteroatoms

Synthesis of Monocyclic Rings with One Heteroatom

Synthesis of Monocyclic Rings with Two or More Heteroatoms

Synthesis of Rings with One Other Heteroatom

Synthesis of Rings with Three or More Heteroatoms

Synthesis of Rings with Two Heteroatoms

Systems with One Heteroatom at a Ring Junction

Three-Membered Rings with One Heteroatom

Three-membered rings with two heteroatoms

Typical Ring Synthesis of a Pyridine Involving Only C-Heteroatom Bond Formation

Typical Ring Synthesis of a Pyrrole Involving Only C-Heteroatom Bond Formation

Unsymmetrical ring-opening, with heteroatom

© 2024 chempedia.info