Heat radiation INDEX

In order to maintain high energy efficiency and ensure a long service life of the materials of construction in the combustion chamber, turbine and jet nozzle, a clean burning flame must be obtained that minimizes the heat exchange by radiation and limits the formation of carbon deposits. These qualities are determined by two procedures that determine respectively the smoke point and the luminometer index. 

Irradiation by fast neutrons causes a densification of vitreous silica that reaches a maximum value of 2.26 g/cm3, ie, an increase of approximately 3%, after a dose of 1 x 1020 neutrons per square centimeter. Doses of up to 2 x 1020 n/cm2 do not further affect this density value (190). Quartz, tridymite, and cristobalite attain the same density after heavy neutron irradiation, which means a density decrease of 14.7% for quartz and 0.26% for cristobalite (191). The resulting glass-like material is the same in each case, and shows no x-ray diffraction pattern but has identical density, thermal expansion (192), and elastic properties (193). Other properties are also affected, ie, the heat capacity is lower than that of vitreous silica (194), the thermal conductivity increases by a factor of two (195), and the refractive index, increases to 1.4690 (196). The new phase is called amorphous silica M, after metamict, a word used to designate mineral disordered by radiation in the geological past (197). 

Chromium (lll)tris(ethylenediamine) Peroxysulfate, [Cr(en)3 ] 2(S O0)3. It was reported by Beacom that this compd can be ignited by flame and exploded by exposing it to ultra-violet>radiation( 36 50A0), followed by heating to 115°. Its method of prepn was not described by Beacom and we could not find this compd listed in Beil or in the alphabetical indexes of CA s (except the listing indicated in Ref 1)... 

Characterization.— The LSFTO powder was calcined at a series of temperatures (1250, 1300, and 1400°C) in air to investigate phase purity and densification behavior. X-ray diffraction (XRD) powder patterns are shown in Fig. 1. The sample is single phase after heating at 1250°C. At the higher sintering temperatures, the lines become sharper and the density increases. The density measured by the Archimedes method was 90.3% relative to theoretical value after annealing at 1400°C for 10 h. The XRD pattern sintered at 1400°C was completely indexed with a cubic unit cell with lattice parameter a = 3.898(8) A and V= 59.2(6) A3. The weak XRD peaks at 31, 43, 55, and 65° 20 are also from the perovskite phase and arise from a small amount of WL radiation in the incident beam. 

Figure 14 shows that the heat loss by radiation becomes insignificant (the oxygen index becomes independent of pressure) at P > 0.3 atm for PMMA, and at P > 2 atm and P > 6 atm for poly(vinyl chloride) and Teflon, respectively. A weak pressure dependence of Y (1/P° ) accounts for extinction of the flame by convective... 

Note that the operative temperature will be the arithmetic average of the ambient and surrounding surface temperatures when the convection and radiation heat transfer coefficients are equal to each other. Another environmental index used in thermal comfort analysis is the effective temperature, which combines the effects of temperature and humidity. Two environments with the same effective temperature evokes the same thermal response in people even though they are at different temperatures and humidities. 

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