Hard acids and bases

The Hard-Soft-Add-Base (HSAB) theory was developed by Pearson in 1963. According to this theory, Lewis acids and Lewis bases are divided into two groups on one hand hard acids and bases, which are usually small, weakly polarizable species with highly localised charges, and on the other hand soft acids and bases which are large, polarizable species with delocalised charges. A selection of Lewis acids, ordered according to their hardness in aqueous solution is presented in Table 1.3. 

Displacement reactions and the concept of soft and hard acids and bases. Struct. Bonding (Berlin), 1966,1,221-233(19). 

Soft and hard acids and bases principle, 2, 1040 Soft-tissue calcification, 6,597 Sogrenite structure, 6, 849 Soils... 

Hudson RF (1966) Displacement Reactions and the Concept of Soft and Hard Acids and Bases. 1 221-223... 

According to Yatsimirskii, group (2) and (3) species are equivalent to Pearson s hard acids and bases, and group (4), (5) and (6) species correspond to Pearson s soft acids and bases. This classification is of more value than HSAB theory to our subject. It can be seen that all cementforming anions come from group (3) and cations from groups (3), (4) and (5). Thus, the bonding in cement matrices formed from cation-anion combinations is not purely a but contains some n character. 

Hapticity. 629, A77 Hard acids and bases, 344-355 Hard-soft acid-base (HSAB) interaction, 351 Hartree-Fock method, 20 Heavier transition metals, 587-588... 

Finally the plate is tested on heat expansion coefficient, temperature shock resistance, temperature stress (6,000 hours at 650°C), density, E-modulus (92 x 103 N/mm2), flexural strength, impact resistance, Knoop hardness, acid and base resistance. The heating element is insulated with a compressed mixture of powder and fibre which contains aluminium oxide and silicon oxide. In the middle the element contains a so-called Stabausdehnungsbegrenzer (= expansion limiter), which automatically switches the element off in case the temperature exceeds a certain pre-set value. 

Model Definition. The HSAB model classifies Lewis acids (electrophiles) and bases (nucleophiles) as either "hard" or "soft." Hard acids and bases are relatively small, and exhibit low polarizability and a comparatively low tendency to form covalent bonds. Soft acids and bases have the opposite characteristics (24). Stated simply, the model postulates that hard acids react most readily with hard bases, and soft acids react most readily with soft bases (26). 

Revised version of a talk, given at the Symposium on Soft and Hard Acids and Bases , arranged by Cyanamid European Research Institute, Cologny (Geneva), May 10.-12., 1965. 

The concept of soft and hard acids and bases (7), which is in effect an extension of the Chatt-Ahrland classification (2) of A and B metals, is applied in the 1963 paper by Pearson (7) particularly to equilibria involving mainly inorganic systems. This paper follows an earlier discussion by Edwards and Pearson (3) of the Swain-Edwards equation (4) (1) for nucleophilic reactivity. 

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