Halides solids

S. C. Lee and R. H. Holm, Nonmolecular metal chalcogenide/halide solids and their molecular cluster analogues. Angew. Chem. Int. Ed. 29 (1990) 840. 

Markham, J. M., 1966. F-centers in alkali halides, Solid State Phys., Suppl. 8. 

In our lab, R.T.Ds are experimentally determined for the 3 phases by pulse injections of radioactive tracers in the real medium gaseous Ar or Kr liquid organometallic complexes, or halides solid neutron-irradiated metal catalysts. 

Let us take as an example the formation of alkali metal halides (solid), MX, from the solid metal, M, and one-half mole of gaseous elemental halogen, X2. Indicating the energy change associated with this reaction by Q one may write... 

Electronic Structure of Solids Fluorides Solid-state Chemistry Halides Solid-state Chemistry Macrocyclic Ligands Metallic Materials Deposition Metal-organic Precursors Oxides Solid-state Chemistry Periodic Table Trends in the Properties of the Elements Sol-Gel Synthesis of Solids Sohds Characterization by Powder Diffraction Structure Property Maps for Inorganic Solids Superconductivity Thin Film Synthesis of Solids. 

Cn atoms can occnpy any one of 56 possible positions. The occupancy varies with temperature, and above room temperature, the phase shows high solid-state conductivity, in this case owing to mobile Cu + ions see Halides Solid-state Chemistry). 

Based in part on the article Halides Solid State Chemistry by Gordon J. Miller which appeared in the Encyclopedia of Inorganic Chemistry, First Edition. 

Coordination Chemistry History Coordination Numbers Geometries Copper Inorganic Coordination Chemistry Gold Organometallic Chemistry Halides Solid-state Chemistry Photochemistry of Transition Metal Complexes. 

Preparation and Identification of Divalent Lanthanide Ions as Dilute Solutes in Alkaline Earth Halide Solid Solutions... 

Fiji. 7.17. Vicki A t)l RMgX us a function of ky. The ploik-d curves are dcicrinined hv equation (/.2hi. Daia lor all nine rcavliniis ol Iv pica I alkyl halides (solid mats) conform lo [his equation tor rK near ID s. bln the data tor inv 1. arvl. and cvclopropyl halides (open ovals) do not. Tins plot is redrawn and aupnienied troin Root. Hill, and Whitesides ks. ... 

Kig. 7.17. Yield A of RMgX as a function of kQ. The plollcd curves are dcicrniincd by equation (7.2, i). Data for all nine reactions of typical alky halides (.solid ovals) conform to this equation for rn near 10 s. but the data for vinyl, ttryl. and cvclopropyi halides (open ovals) do not. This plot is redrawn and augmented frotit Rttot. Hill, and... 

A benzyl halide solid support If (Table 1) has been reported [77] that affords anchoring groups which are less labile than trityl anchors Ib-le but more labile than anchors to chloromethyl-PS (la). Resin If has been used to prepare amides and sulfonamides by reaction with an amine followed by acylation or sulfonylation, respectively, and cleavage using 95% TFA. When the same reaction sequence was conducted on an analogous resin Ig prepared from Tentagel AC (acid-cleavable linker), the products could be cleaved under milder conditions (5% TFA) because of the greater stability... 

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