Halides metal hydrides

Metal halide Metal hydride Metal hydrides... [Pg.608]

See related metal halides, metal hydrides See other amination incidents... [Pg.1347]

ACID ANHYDRIDES, ACYL HALIDES, ALKALI METALS ALKYLALUMINIUM DERIVATIVES, ALKYLNON-METAL HALIDES COMPLEX HYDRIDES, METAL HALIDES, METAL HYDRIDES METAL OXIDES, NON-METAL HALIDES (AND THEIR OXIDES)... [Pg.417]

ALKYLALUMINIUM DERIVATIVES ALKYLNON-METAL HALIDES COMPLEX HYDRIDES METAL HALIDES METAL HYDRIDES METAL OXIDES... [Pg.2619]

GC has been used extensively for the separation and determination of volatile organic molecules, and most aspects of this application area are fully documented in monographs on this technique. In the inorganic trace analysis area, however, fewer species possess the required volatility, and applications tend to be limited to the separation of volatile species of low molecular weight (such as methyl derivatives of As, Se, Sn, Hg) and the separation of semi-volatile organo-metals, metal halides, metal hydrides, metal carbonyls and metal chelates. For organo-metal species, the type of detection system required varies with the nature of the analyte, and the options include electron capture detection, flame photometric detection (sometimes ICP), AAS and MS. [Pg.19]

Figure 4,4 Standard enthalpies of formation (A// and lattice energies (plotted as —t/O for alkali metal halides and hydrides.

The alkali metal halides, particularly NaCl and KCl, find extensive application in industry (pp. 71 and 73). The hydrides are frequently used as reducing agents, the product being a hydride or complex metal hydride depending on the conditions used, or the free element if the hydride is unstable. Illustrative examples using NaH are ... [Pg.83]

Alcohols react with metal hydrides, MH, and with hydrogen halides, HX, but in very different ways. Proton transfer is involved in both reactions, but different molecules act as the proton donor and acceptor. [Pg.123]

The saline hydrides are white, high-melting-point solids with crystal structures that resemble those of the corresponding halides. The alkali metal hydrides, for instance, have the rock-salt structure (Fig. 5.39). [Pg.704]

Acyl halides are reduced to alcohols by L1A1H4 or NaBH4, as well as by other metal hydrides (Table 19.5), but not by borane. [Pg.1551]

See related NON-METAL HALIDES, NON-METAL HYDRIDES 0122. Boron tribromide... [Pg.66]

See other inorganic acids, non-metal halides, non-metal hydrides... [Pg.1507]

Hydrides of variable composition are not only formed with pure metals as solvents. A large number of the binary metal hydrides are non-stoichiometric compounds. Non-stoichiometric compounds are in general common for d,f and some p block metals in combination with soft anions such as sulfur, selenium and hydrogen, and also for somewhat harder anions like oxygen. Hard anions such as the halides, sulfates and nitrides form few non-stoichiometric compounds. Two factors are important the crystal structures must allow changes in composition, and the transition metal must have accessible oxidation states. These factors are partly related. FeO,... [Pg.221]