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Aliphatic halides

Reaction of the dilithiated species 416 and 419 with alkyl halides, aliphatic and aromatic aldehydes, and TMSC1 leads to products 421 and 422 in modest yields (Scheme 129) [83TL4735 86JCR(S)20]. In cases of the N-benzyl amides corresponding to 415 and 418, small amounts of benzylic functionalization is observed (see also later). The methyl and carbinol derivatives corresponding to 421 and 422 were quantitively hydrolyzed into useful synthons 423 and 424, and 425 and 426, respectively. [Pg.259]

HEXYL CARBITOL (112-59-4) CioH 0 Combustible peroxidizable liquid (flash point 285°F/141°C cc). Forms unstable peroxides on exposure to air. Violent reaction with oxidizers, boron trifluoride permanganates, peroxides and hydroperoxides, ammonium persulfate, bromine dioxide, sulfuric acid, nitric acid, perchloric acid, and other strong acids. Incompatible with acids, acyl halides, aliphatic amines, alkalis, boranes, isocyanates. On small fires,... [Pg.550]


See other pages where Aliphatic halides is mentioned: [Pg.231]    [Pg.58]    [Pg.58]    [Pg.138]    [Pg.145]    [Pg.172]    [Pg.173]    [Pg.179]    [Pg.181]    [Pg.319]    [Pg.320]    [Pg.347]    [Pg.347]    [Pg.347]    [Pg.348]    [Pg.348]    [Pg.348]    [Pg.349]    [Pg.349]    [Pg.349]    [Pg.353]    [Pg.358]    [Pg.448]    [Pg.449]    [Pg.464]    [Pg.670]    [Pg.671]    [Pg.693]    [Pg.921]    [Pg.1040]    [Pg.1040]    [Pg.1045]    [Pg.1058]    [Pg.1061]   


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Acid halides aliphatic

Aliphatic Alkanes, Alkenes, Alkynes, and Alkyl Halides

Aliphatic acyl halides

Aliphatic halides, electron attachment

Aliphatic halides, hydrogenolysis

Aliphatic halides, oxidative addition

Aliphatic halides, purification

Alkyl halides aliphatic

Alkyl halides nucleophilic aliphatic

Carboxylic acid halides: aliphatic, synthesis

Carboxylic acid halides: aliphatic, synthesis aromatic

Coupling of Activated Aliphatic Halides with Carbonyl Compounds

Cross-Coupling of Aryl Halides with Aliphatic Alcohols

Halides, aliphatic base effect

Halides, aliphatic catalyst effect

Halides, aliphatic selectivity

Nucleophilic Aliphatic Substitution Preparation of Alkyl Halides

Oxidative addition of aliphatic halides

Reactions of Aryl Halides with Aliphatic Alcohols

Saturated Aliphatic Halides

Triphenylphosphine, aliphatic halide

With Aliphatic Halides

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