Gold organic synthesis

Uson, R., Lagrma, A. and Vicente, J. (1977) Aryl-Gold Chemistry. Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 7(5), 463-496. 

Organic synthesis Sulfur mustard (HD) 1.18 Pharmaceuticals Sulfur dyes Insecticides Rubber vulcanization Polymerization catalyst Hardening of soft woods Extraction of gold from ores... 

Silver belongs to the late transition metals and, like gold, favors coordination to C=C triple bonds. A lot of silver-containing organometallic complexes, where silver-alkyne interactions assist the assembly of the complexes, are known. None of these complexes, however, was applied to efficient carbon-carbon bond formation in organic synthesis. 

Uses On gold courses for managing and treating fungal disease chemical research and organic synthesis. 

Cyanogen bromide is used in organic synthesis, as a rodent poison, and as a reagent for extracting gold as its cyanide salt. 

Addition of Active Methylenes In the previous decade Cinellu et al. studied certain 1,3-dicarbonyl gold complexes and some applications in organic synthesis were subsequently proposed [78]. Intermolecular addition of activated methylene compounds to alkenes was developed by using AuCl3/AgOTf [79]. 

A phenol synthesis reaction induced by gold catalysts without steric limitations for the substituents was also reported [169]. These results provided a very helpful tool for organic synthesis of a large variety of derivatives such as biaryls, iso-chromanes, benzofurans, tetrahydroisoquinolines and other natural products [133, 170, 171]. 

The gold-catalysed synthesis of highly substituted arenes or benzofurans from furans has proved to be a powerful tool for organic synthesis.76 Experimental evidence has now been provided for the formation of (47) via (46). 

Shore G, Yoo W-J, Li C-J et al (2009) Propargyl amine synthesis catalysed by gold and copper thin films by using microwave-assisted continuous-flow organic synthesis (MACOS). ChemEur J 16 126-133... 

Use Organic synthesis, parasiticide, fumigating compositions, rat exterminants, cyaniding reagent in gold extraction processes. 

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