Gold complexes synthesis

In contrast, this complex does not undergo homoleptic rearrangement in solution. It was the first diorganocarbene gold complex synthesized [68],... 

Figure 1.2 Amidine ligands used in the synthesis of terta-, tri-, and dinuclear gold complexes.

Abdou, H. (2006) PhD. Thesis New Chemistry with Gold-Nitrogen Complexes Synthesis and Characterization of Tetra-, Tri-, and Dinuclear Gold(I) Amidinate Complexes. Oxidative-Addition to the Dinuclear Gold (I) Amidinate, A M University, Texas. 

Barber J., Elduque, A., Gimenez, R., Lahoz, F.J., Oro, L.A. and Serrano, J.L. (1998) (Pyrazolato)gold complexes showing room-temperature columnar mesophases. Synthesis, properties, and structural characterization. Inorganic Chemistry, 37, 2960-2967. 

Byabartta, P. (2007) Gold(l)-gold(III)-4,4 -bpy-phosphrne complexes synthesis and multinuclear NMR study. Transition Metal Chemistry, 32, 314. 

In addition to the simple reaction of a poly dentate ligand with [Au(C6F5)(tht)] the other versatile synthesis of di- and trinudear derivatives is the use of gold complexes as ligands. 

Bardaji, M Laguna, A., Laguna, M. and Merchan, F. (1994) Methyl dithiocarbamate gold(l) and gold(lll) complexes. Synthesis and reactivity with amines. Inorganica Chimica Acta, 215 (1-2), 215-218. 

Williams, D.B.G., Traut, T, Kriel, F.H. and van Zyl, W.E. (2007) Bidentate amino-and iminophosphine ligands in mono-and dinuclear gold(I) complexes Synthesis, structures and AuCl displacement by AuC E . Inorganic Chemistry Communications, 10(5), 538-542. 

Kitadai, K., Takahashi, M., Takeda, M., Bhargava, S.K., Priver, S.Fl. and Bennett, M.A. (2006) Synthesis, structures and reactions of cyclometalated gold complexes containing (2-diphenylarsino-n-methyl)phenyl (n = 5, 6). Dalton Transactions, (21), 2560—2571. 

Uson, R., Laguna, A. and Vicente, J. (1976) Dihaloperhalophenyl(triethylphosphine) gold(III) complexes. Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 6(4), 293—305. 

Luminescent gold(l) acetylide complexes. Photophysical and photoredox properties and crystal structure of [ Au(C = CPh) 2 (p-Ph2PCH2CH2PPh2)]. Journal of the Chemical Society, Dalton Transactions, 2929-2932 (d) Che, C.-M., Wong, W.-T., Lai, T.-F. and Kwong, H.-L. (1989) Novel luminescent binuclear gold(I) isocyanide complexes. Synthesis, spectroscopy, and X-ray crystal structure of Au2(dmh)(CN)2 (dmb = 1,8-di-isocyano-p-menfhane). Journal of the Chemical Society, Chemical Communications, 243-244. 

The number of gold complexes containing tertiary phosphines, arsines, or stibines as ligands is large because of the wide use of the fragment AuL+, mainly with L = PPh3, in the synthesis of... 

Due to the lability of the Ag-Ccm-bene bond, silver NHC complexes of type 25 are useful agents for the NHC transfer reactions to transition metals. The preparation of silver NHC complexes using the Ag20 method and the transfer of the NHC ligand to other metal centers like gold has become a standard procedure in NHC complex synthesis. The Ag20 method often gives access to NHC complexes where alternative syntheses are tedious or not successful. 

Apart from thiolate ligands, S, Se or -containing fulvalene derivatives have been employed as electron donors in the synthesis of gold complexes. The combination of tetrathiafulvalene, TTF, with the gold complex bis(pyrazine-2,3-diselenolate)aurate... 

The use of other potential bidentate ligands also permits the synthesis of cyclic trinuclear gold complexes that form, by stacking, supramolecular assemblies. This is the case for the trinuclear complex [Au3(NC5H4)3] [47] that crystallizes in two... 

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