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Glycals glycosylation

The glycal epoxide method turned out to be useful for the construction of complex 2-branched [3-aryl glycosides, which are salient features of the potent antibiotic vancomycin [75a]. Glycal epoxide glycosylation with sodium salts of indoles pro-... [Pg.299]

A conceptually new direct oxidative glycosylation with glycal donors, employing a reagent combination of triflic anhydride and diphenyl sulfoxide, has recently been reported by Gin [83], This new 3-glycosylation method works very well with hindered hydroxy nucleophiles, including sterically shielded carbohydrate hydroxy systems, and can be run on large scales. [Pg.302]

Oxathiins derived from the cyclic diacylthione (60) and glycals by a cycloaddition reaction yield glycosides on desulfurization, offering an alternative approach to glycosyl transfer <96AG(E)777>. [Pg.312]

Because of the high C - F bond energy, glycosyl fluorides are stable in comparison to the other glycosyl halides, and this character has attracted much attention. They have been prepared in many different ways. One of them, rather classical, is through addition of the elements of HF (for example, HF in benzene ), BrF, or IF to per-O-acylated glycals. ... [Pg.94]

Glycals have been widely used as glycosyl donors, especially for the synthesis of 2-deoxyglycosides 45b 47 In addition, they can be readily converted into 2,3-unsaturated... [Pg.38]

Glycals can be transformed into 1,6-anhydro sugar derivatives by intramolecular cyclization in the presence of Lewis and Brpnsted acids, a reaction that has been termed the intramolecular Ferrier glycosylation.168 Sharma el al.169 showed that a montmorillonite clay-supported silver reagent can be an efficient catalyst for this transformation. The 1,6-anhydro-2,3-dehydro sugars obtained were then selectively dihydroxylated to furnish 1,6-anhydro saccharides. [Pg.79]

E. Wieczorek and J. Thiem, Preparation of modified glycosyl glycerol derivatives by glycal rearrangement, Carbohydr. Res., 307 (1998) 263-270. [Pg.88]

Fig. 4. Sugar derivatives serving as acceptors for glycosylation by dextransucrase alditols, aldosuloses, aldonic acids, a fructose dianhydride, and a glycal.71... Fig. 4. Sugar derivatives serving as acceptors for glycosylation by dextransucrase alditols, aldosuloses, aldonic acids, a fructose dianhydride, and a glycal.71...

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See also in sourсe #XX -- [ Pg.144 ]




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Glycal

Glycals as glycosyl donor

Glycosyl fluorides preparation, from glycals

Use of glycals as direct glycosyl donors haloglycosylation

Using glycals to form epoxide glycosyl donors 1,2-anhydrosugar glycosylation

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