Glycals glycoconjugates

The Glycal Assembly Method on Solid Supports Synthesis of Oligosaccharides and Glycoconjugates... 

Seeberger, P. H. Bilodeau, M. T. Danishefsky, S. J. Synthesis of Biologically Important Oligosaccharides and Other Glycoconjugates by the Glycal Assembly Method, Aldrichim. Acta 1997, 30, 75. 

J. W. Gillard Development of novel antiviral nucleoside analogues S. J. Danishefsky Glycals in the synthesis of oligosaccharides and glycoconjugates... 

Seeberger PH, Bilodeau MT, Danishefsky SJ. Synthesis of biologically important oligosaccharides and other glycoconjugates by the glycal assembly method. Aldrichim. Acta. 1997 30 75-92. Gin D. Dehydrative glycosylation with 1-hydroxy donors. J. Carb. Chem. 2002 21 33-52. 

Seeberger, P. H., Danishefsky, S. J. (1998). Solid-phase synthesis of oligosaccharides and glycoconjugates by the glycal assembly method A five year retrospective, Acc. Chem. Res., 31 685. 

DusopropylsUyl linkers on polystyrene resins have been used in solid-phase synthesis of oligosaccharides and glycoconjugates via the glycal assembly method (eq 6). ... 

Danil994 Danishefsky, S.J., Randolph, J.T. and Roberge, J.Y., Application of the Glycal Assembly Method in the Solid Phase a New Strategy for the Synthesis of Oligosaccharides and Glycoconjugates, Polym. Prepr., 35 (1994) 977-978. 

The extension of this procedure to the glycosylation of indoles was pursued in the context of rebeccamycin [40]. In this example, deprotonation of the differentiated indolocarbazole 72 followed by exposure of the resultant anion to glycal-epoxide 73 gave a 48% yield of the glycosylated product 74. Subsequent 2,2 -bis indole bond formation and deprotection yielded the glycoconjugate rebeccamycin (44). 

Danishefsky, S. J. Bilodeau, M. T. Glycals in Organic Synthesis The Evolution of Comprehensive Strategies for the Assembly of Oligosaccharides and Glycoconjugates of Biological Consequence. Angew. Chem. Int. Ed. 1996, 55, 1380-1419. 

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