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Glucosides, reactions

C-Glucosidation. Reaction of the protected a-D-glucopyranosyl chloride 1 with silyl enol ethers activated with AgOTf results in a-C-glucosyl esters or ketones. [Pg.282]

For more references to Imines, see sections titled Formation and Reactions of Acetals and Related Species , Reactions of Glucosides , Reactions of Ketenes , and... [Pg.14]

C7H6O2 Oily liquid of aromatic odour b.p. 196°C. (t is prepared by the action of chloroform and caustic potash on phenol (the Reimer-Tiemann reaction) or by the oxidation of the glucoside salicin. It is easily reduced to salicyl alcohol or oxidized to salicylic acid. [Pg.350]

They are highly specific in their reactions, e.g., maltose attacks the a glucosidic link (which occurs in maltose), but is without action on the 3-glucosidic links. [Pg.509]

When dextrose is heated with methanol containing a small amount of anhydrous hydrogen chloride, a-methyl-D-glucoside is obtained in good yield and can be isolated by crystallization. Similar reactions occur with higher alcohols, but the reaction products are more difficult to isolate by crystallization. Dextrose reacts with acid anhydrides in the presence of basic catalysts, yielding esters. Complete reaction gives the pentaacylated derivative. [Pg.289]

Several other methods for the introduction of halo atoms at C-6 in hexose derivatives have been known since the late 1920s. One of the earlier methods involved the reaction of methyl 2,3,4-tri-0-acetyl-6-0-trityl-a-D-glucopyranoside with phosphorus pentachloride which resulted only in an 8% overall yield of methyl 6-chloro-6-deoxy-a-D-glucoside (57). In contrast, the reaction of methyl 2,3,4-tri-0-acetyl-6-0-trityl-a-D-altropyranoside with phosphorus tribromide and bromine afforded a 73% yield of the corresponding 6-bromo-6-deoxy derivative (91). [Pg.199]


See other pages where Glucosides, reactions is mentioned: [Pg.165]    [Pg.221]    [Pg.595]    [Pg.432]    [Pg.125]    [Pg.94]    [Pg.41]    [Pg.52]    [Pg.169]    [Pg.79]    [Pg.72]    [Pg.165]    [Pg.221]    [Pg.595]    [Pg.432]    [Pg.125]    [Pg.94]    [Pg.41]    [Pg.52]    [Pg.169]    [Pg.79]    [Pg.72]    [Pg.215]    [Pg.451]    [Pg.369]    [Pg.286]    [Pg.293]    [Pg.297]    [Pg.15]    [Pg.822]    [Pg.330]    [Pg.406]    [Pg.15]    [Pg.198]    [Pg.152]    [Pg.171]    [Pg.259]    [Pg.490]    [Pg.109]    [Pg.128]    [Pg.322]    [Pg.322]    [Pg.323]    [Pg.324]    [Pg.324]    [Pg.353]   
See also in sourсe #XX -- [ Pg.4 ]

See also in sourсe #XX -- [ Pg.4 ]

See also in sourсe #XX -- [ Pg.4 ]

See also in sourсe #XX -- [ Pg.4 , Pg.5 , Pg.6 ]

See also in sourсe #XX -- [ Pg.2 , Pg.3 , Pg.3 , Pg.4 , Pg.4 , Pg.96 , Pg.97 , Pg.99 ]




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Reaction of malvidin-3-glucoside

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Reactions of Glucosides

Reactions of Glucosides and Nucleosides

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