Generator selection, design considerations

The choice of a turboexpander load may be influenced by the desire to optimize refrigeration. In other words, a dynamometer load may be chosen over a generator load due to speed considerations. Additionally, there are other constraints imposed on optimal design. Factors such as impeller peripheral velocity (tip speed), bearing design, axial load balance, material selection, and manufacturing methods (which have greatly improved in the recent decades) all have an influence. 

Now let us consider utility failure as a cause of overpressure. Failure of the utility supphes (e.g., electric power, cooling water, steam, instrument air or instrument power, or fuel) to refinery plant facihties wiU in many instances result in emergency conditions with potential for overpressuring equipment. Although utility supply systems are designed for reliability by the appropriate selection of multiple generation and distribution systems, spare equipment, backup systems, etc., the possibility of failure still remains. Possible failure mechanisms of each utility must, therefore, be examined and evaluated to determine the associated requirements for overpressure protection. The basic rules for these considerations are as follows ... 

In contrast to considerations of 50 years ago, today carbene and nitrene chemistries are integral to synthetic design and applications. Always a unique methodology for the synthesis of cyclopropane and cyclopropene compounds, applications of carbene chemistry have been extended with notable success to insertion reactions, aromatic cycloaddition and substitution, and ylide generation and reactions. And metathesis is in the lexicon of everyone planning the synthesis of an organic compound. Intramolecular reactions now extend to ring sizes well beyond 20, and insertion reactions can be effectively and selectively implemented even for intermolecular processes. 

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