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Generalization of specific

The methodology for synthesis of isoindoles is not as thoroughly explored as that of pyrroles and indoles and there is less information about the generality of specific methods. Nevertheless, reaction patterns for cyclizative condensation are similar to those for pyrroles and indoles. Generation of o-acylbenzylamines generates isoindoles. Several l-arylisoindoles were prepared in two steps from (7) by a Friedel-Crafts reaction followed by release of the amino group from the phthalimide by hydrazinolysis (Scheme 24) <64JA4152>. [Pg.128]

Quantitative generalization of specific parameters such as the compression index cannot be made on the basis of location alone. Available data indicate that wide ranges in the value of specific parameters are common in each of the locations (Hermann, 1974 Davie et al., 1978 and Richards and Chaney, 1981). [Pg.268]

The obvious defect of classical trajectories is that they do not describe quantum effects. The best known of these effects is tunnelling tln-ough barriers, but there are others, such as effects due to quantization of the reagents and products and there are a variety of interference effects as well. To circumvent this deficiency, one can sometimes use semiclassical approximations such as WKB theory. WKB theory is specifically for motion of a particle in one dimension, but the generalizations of this theory to motion in tliree dimensions are known and will be mentioned at the end of this section. More complete descriptions of WKB theory can be found in many standard texts [1, 2, 3, 4 and 5, 18]. [Pg.999]

There is increasing evidence that the ionisation of the organic indicators of the same type, and previously thought to behave similarly, depends to some degree on their specific structures, thereby diminishing the generality of the derived scales of acidity. In the present case, the assumption that nitric acid behaves like organic indicators must be open to doubt. However, the and /fp scales are so different, and the correspondence of the acidity-dependence of nitration with so much better than with Hg, that the effectiveness of the nitronium ion is firmly established. The relationship between rates of nitration and was subsequently shown to hold up to about 82 % sulphuric acid for nitrobenzene, />-chloronitrobenzene, phenyltrimethylammonium ion, and p-tolyltrimethylammonium ion, and for various other compounds. ... [Pg.22]

The comparison plot offers a particularly simple and direct means of comparing the shapes of a pair of isotherms but for more general applications which involve a numt>er of samples of a solid covering a wide range of specific surface, the a,-method is preferable. The j-curve represents a convenient way of recording and using the reference isotherm. [Pg.100]

General conclusions determination of specific surface from adsorption isotherms... [Pg.102]

The general formula for the initiator species can be written H B, where the degree of separation or ion pairing depends on the polarity of the medium and the possibility of specific solvation interactions. If we represent the equilibrium constant for the reactions in (6.DD) and (6.EE) by K, the initiator concentration can be written as... [Pg.412]

In general, any o-nitiobenzyl ketone 01 o-aminobenzyl ketone can be converted to a 2-substituted indole. There are a variety of specific examples of such syntheses, although there are not any truly general means of generating these kinds of starting materials. [Pg.87]

In general, LPG specifications involve limits for physical properties. Consequentiy, the composition of the commercial-grade products varies between wide limits. Physical properties of the principal components of LPG are summarized in Table 1 (1). [Pg.182]

The general sales specification under which maleic anhydride is sold ia the United States specifies a white fused mass or briquettes of 99.5% minimum assay and 52.5°C minimum crystallisation poiat. The melt color specification is 20 APHA maximum with a maximum APHA color of 40 after two hours of heating at 140°C. Four grams of maleic anhydride ia 10 milliliters of water are to be completely soluble. The resulting solution is to be colodess. The acidity resulting from maleic acid is allowed to be a maximum of 0.2%. [Pg.459]

Fumaric acid is sold as resia-grade and food-grade. The general sales specification under which resia-grade fumaric acid is sold ia the United States specifies white, crystalline granules with a minimum assay of 99.6% and maximum ash content of 0.05%. The moisture specification is 0.3% maximum with < 10 ppm heavy metals. The color of a 5% solution ia methanol is to be less than 10 APHA. Food-grade fumaric acid calls for somewhat lower impurity levels. Particle size and particle size distribution are important ia many appHcations. [Pg.459]

Microwave tubes for other ISM bands are not commonly available as tubes designed specifically for ISM use. Available tubes, generally of military and communications types, are more expensive. Reasonably priced tubes exist at 0.915 GHz at high (>25 kW) power, but not at 5.8 GHz and higher, or at... [Pg.342]

The bulk of the patent specification is the disclosure, the text and illustrations that describe the claimed invention in detail and explain how the claimed invention differs from the prior art. Modem patent disclosures contain a summary of the claimed invention, a description of the background of the invention, a general description of the way in which the invention is made and used, specific examples, and, where appHcable, drawings of the invention in general or specific embodiments. The technical information provided in a patent specification may be used without infringing the patent only practicing the invention defined in the claims within the term and territory of the patent grant is forbidden. Because much of the information in patent specifications is never pubHshed in refereed journals or other nonpatent media, patent disclosures are an invaluable part of the technical Hterature. [Pg.45]

There are no generally accepted specifications manufacturers set their own specifications for hydroxyl number range, melt viscosity, water content, etc. Typical properties of Du Pont Terathane PTMEG are Hsted in Table 2, and selected thermal properties are given in Table 3 (260). For all grades, water content is <0.015 wt % ash, <0.001 wt % iron, <1 ppm peroxide, <5 ppm as H2O2 and flash point TOC is >163°C. [Pg.366]


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See also in sourсe #XX -- [ Pg.26 ]




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