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General Steps in a Chemical Analysis

The analytical process often begins with a question such as Is this water safe to drink or Does emission testing of automobiles reduce air pollution A scientist translates such questions into the need for particular measurements. An analytical chemist then chooses or invents a procedure to carry out those measurements. [Pg.9]

When the analysis is complete, the analyst must translate the results into terms that can be understood by others. A most important feature of any result is its limitations. What is the statistical uncertainty in reported results If you took samples in a different manner, would you obtain the same results Is a tiny amount (a trace) of analyte found in a sample really there or is it contamination Once all interested parties understand the results and their limitations, then people can draw conclusions and reach decisions. [Pg.9]

Formulati ng Translate general questions into specific questions to be answered [Pg.9]

Search the chemical literature to find appropriate procedures or, if necessary, devise new procedures to make the measurements. [Pg.9]

Select representative material to analyze, as described in Box 0-1. If you begin with a poorly chosen sample or if the sample changes between the time it is collected and the time it is analyzed, results are meaningless. Garbage in— garbage out  [Pg.9]

Sampling Sampling is the process of selecting representative material to [Pg.7]


It is worth remarking that a gas sensor array is a mere mathematical construction where the sensor outputs are arranged as components of a vector. Arrays can also be utilized to investigate the properties of chemical sensors, or even better, the peculiar behaviour of a sensor as a component of an array. In this chapter, the more common sensor array methodologies are critically reviewed, including the most general steps of a multivariate data analysis. The application of such methods to the study of sensor properties is also illustrated through a practical example. [Pg.147]

The evaluation of absolute rate coefficients of elementary reactions (hereafter referred to only as rate coefficients) is one of the most important steps in the kinetic analysis. Comparison of such values with our general chemical knowledge of radical reactions serves first as a check on the kinetic analysis and second, if shown to be reliable, they may be used in the kinetic analysis of other systems. It is often possible and useful to evaluate the rate coefficients directly in oxidation reactions as well as in much more simplified systems where many of the competing steps have been eliminated. [Pg.13]

In a chemical sense, what relates molecular subunits with their assembly product To answer this question precisely is to define self-assembly. From a qualitative standpoint, we can state that the two sets of molecules are related by a complex series of intertwining equilibria some of them dead-ends, some of them leading as directly to the assembly product as possible. As a step toward analyzing this type of complex system, we recently described a general, semiquantitative analysis of self-assemblies. This probabilistic approach" focuses on the options available to each molecular subunit as the assembly occurs and engenders a common frame of reference by which the efficiency of all assemblies leading to discrete species can be compared. [Pg.1375]

To illustrate the generality of reversibility and the equilibrium expression, we extend our kinetic analysis to a chemical reaction that has a two-step mechanism. At elevated temperature NO2 decomposes into NO and O2 instead of forming N2 O4. The mechanism for the decomposition reaction, which appears in Chapter 15. [Pg.1140]

Areas in which additional information is still needed relates to the role and relative importance of different adducts and the mechanisms by which they initiate cells. General principles are developing which will allow better predictions to be made at each of the stages of chemical carcinogenesis outlined in Table I. The ultimate goal therefore, would be, by a combined analysis of all these steps, to predict accurately the carcinogenicity of newly discovered or untested PAH derivatives. [Pg.206]


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In general

Steps in Analysis

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