Garnet microwave

Dysprosium (Dy) Owing to its important thermal neutron cross section, dysprosium is used to produce control rods in nuclear reactors and also as a neutron flux measurement. The alloy Tb Dy Fe, is used as a magnetostrictive material. The alloy Nd-Fe-B is a permanent magnet. Finally, dysprosium is also used as phosphors, catalysts, and garnet microwave devices. 

Erbium (Er) Erbium is used in lasers, phosphors, garnet, microwave devices, ferrite bubbles devices, and catalysts. 

Group III with electronic configuration 5s 4d . The principal ore is gadolinite (a silicate also containing lanthanides). Y2O3 containing Eu is used as a red phosphor in colour television. Yttrium iron garnets are used as microwave filters. 

Yttrium oxide also is used to produce yttrium-iron-garnets, which are very effective microwave filters. 

Gadolinium yttrium garnets are used in microwave applications and gadolinium compounds are used as phosphors in color television sets. 

Garnets have played an important role in the development of highly sophisticated microwave devices since the development of yttrium—iron garnet, yttrium iron oxide [12063-56-8]. The iron is strongly constrained to be trivalent in order to maintain electrical neutraUty in the crystal, which is essential for low microwave losses. Garnets have lower values of saturation magneti2ation than spinels, but provide superior performance in microwave devices because they have a narrower resonance line width. 

So-called hexagonal ferrites such as BaFe -Oi9 are ferrimagnetic and are used to construct permanent magnets. A third type of ferrimagnetic mixed oxides are the garnets, Mj FejOjj, of which the best known is yttrium iron garnet (YIG) used as a microwave filter in radar. 

This method emplosrs a molten flux which dissolves the material and re-deposits it upon a seleeted substrate. That is, the molten flux acts as a transport medium. The temperature of the flux can be varied to suit the material and to promote high solubility of the solute material in the molten solvent. One example is YIG", yttrium iron garnet, i.e.- Y3FesOi2 -This material is used in the Electronics Industry as single crystals for microwave generating devices. It can be grown via the molten flux method. 

Garnets are important gems, abrasives, microwave systems components, magnetic bubble memories, and laser hosts. For the latter, yttrium aluminum garnet is the most important. It also plays an important role in aircraft turbines where it forms a protective coating on the turbine blades. 

The most important apphcation of this metal is as control rod material for shielding in nuclear power reactors. Its thermal neutron absorption cross section is 46,000 bams. Other uses are in thermoelectric generating devices, as a thermoionic emitter, in yttrium-iron garnets in microwave filters to detect low intensity signals, as an activator in many phosphors, for deoxidation of molten titanium, and as a catalyst. Catalytic apphcations include decarboxylation of oxaloacetic acid conversion of ortho- to para-hydrogen and polymerization of ethylene. 

The oxide is used in phosphors that form red color in color television tubes. Also, it is used in gas mantles and acetylene hghts. Other uses are in yttrium-iron garnets for microwave filters in lasers, and as a stabdizer for high temperature in refractories. 

A further important feature of the garnets is their high electrical resistivity resulting in a high Q suitable for certain microwave devices. This is because they... 

Most transition elements are available in a pure state as metals which can be dissolved in acids. A mixture of nitrates can be evaporated to dryness and calcined to form precursor oxide mixtures for the preparation of spinel and garnet ferrites. Alternatively, mixed oxides, carbonates or oxalates can be precipitated. Microwave ferrites that are required to be of high purity can be prepared by one of these chemical routes. 

In the cases of NiFe204 and the rare earth garnets for microwave use, in which the losses due to conductivity must be minimized, an oxygen atmosphere may be required for sintering so that the concentration of Fe2+ ions is reduced to a very low level. 

An important application for garnets is for isolators in optical communications systems. Reflections from end-faces of components and interconnections in an optical transmission line have a destabilizing effect on the operation of the laser sources and have to be eliminated. This is achieved using an optical isolator , the optical analogue (2 typically in the range 1.30—1.55 /mi) of the microwave isolator described in Section 9.5.5. 

Perhaps more than in most other examples that can be cited of materials exploitation, designing a ferrite for a particular microwave application is a compromise a desired value for a particular parameter is generally achieved at the expense of the optimum values of other parameters. Nevertheless, a select number of spinel and garnet compositions have become favoured for microwave applications. 

Magnetic properties are important in the function of electronic devices. An example is the use of yttrium iron garnet (YIG) in microwave devices. On applying an external magnetic field to a YIG disk, the input, say energy of one particular frequency selectively passes to the output. Thin films based of YIG within which magnetic waves can pass have proven to be useful. The use of lanthanides in magnetic devices as transducers is listed in Table 12.18. 

Small amounts of Y or La are used to dope BaTiC>3 which is the main component of all PTCs (positive temperature coefficient). Demand for PTC thermistors is high. Yttrium iron garnets are used in soft ferrites at very high frequencies (microwave region) for radar equipment. 

Yttrium iron garnet (YIG) is used in devices that process microwaves. Growing YIG and LnIG films on perfect crystals obtained from gadolinium gallium garnet (GGG) is involved in ceramics which have technological applications. 

Yttrium compounds are frequently useful host materials for later Ln + ions, as mentioned in Section 5.4.4 Eu Y2O2S is the standard material for the red phosphor in virtually all colour and television cathode ray tubes, whilst Eu Y203 is used for energy-efficient fluorescent tubes. Yttrium oxide is used to stabilize zirconia (YSZ), yttrium iron garnets (YIG) are used in microwave devices, and of course YBa2Cu307 is the classic warm superconductor. Yttrium, like scandium, is naturally monoisotopic. Y has I = 1/2 though signals can be difficult to observe, valuable information can be obtained from NMR studies. 

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