Free energy, transfer

It has been shown recently (1) that the transfer of urea from water to water-rich water-tetrahydrofuran (THF) mixtures is an entropy-controlled phenomenon (T AS°t > AH°t ), but from water to water-THF mixtures of mole fraction Z2 > 0.20 it is an enthalpy-controlled phenomenon ( AH°t > T AS°t ) moreover, the transfer is energetically favorable in the former case and unfavorable in the latter. A minimum in the standard free energy transfer... 

The transformation of information from one system to another is often almost entropy-free energy transfer, and the information capacity I in binary units is expressed as a function of the probability P... 

Mishustin proposed a strict and accurate method for selective solvation study. The method is based on data of free energy transfer of electrolyte from individual solvent A to mixed solvent A - B. The method takes into account non-ideality of the system, and allows calculation of the concentration of different solvate forms and their dependence on the... 

The first bracket on the left represents the Gibbs free energy transfer of asphaltene molecules and their deformation. The second term represents the interfacial Gibbs free energy, and the second bracket represents various terms for resin contribution to the micellization process. In Example 5.6, an alternative form of Eq. (5.64a) will be presented. 

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