Gibbs free energy, of electron transfer

Correlation between Photocurrent and the Gibbs Free Energy of Electron Transfer... 

The Gibbs free energy of electron transfer is determined by the formal electron transfer potentials associated with the excited state of the metalloporphyrin ( p, ) and the redox couple in the organic phase... 

Figure 11.23. Photocurrent transient responses associated with the photo-oxidation of various ferrocene derivatives (a) and photoreduction of electron acceptors (b) by the ion pair ZnTPPS-ZnTMPyP. Experiments were performed at the water/DCE interface at 0 V (a) and —0.12 V(b). The difference in photocurrent magnitude is connected to the Gibbs free energy of electron transfer (see Table 11.1). Reprinted with permission fromrefs.[101] and [60]. Copyright (2002/2003) American Chemical Society.

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See also in sourсe #XX -- [ , , ]

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