Fourier transform infrared phase

Co concentration was determined by spectrophotometer (Varian Cary 500) at 692 nm wave length, with the sample diluted with a 9 mol/L concentrated HCl solution. NO content in gas phase was obtained by an on-line Fourier transform infrared spectrometer (Nicolet E.S.P. 460 FT-IR) equipped with a gas cell and a quantitative package, Quant Pad. 

Detection in SFC can be achieved in the condensed phase using optical detectors similar to those used in liquid chromatography or in the gas phase using detectors similar to those used in gas chromatography. Spectroscopic detectors, such as mass spectrometry and Fourier transform infrared spectroscopy, are relatively easily interfaced to SFC compared to the problems observed with liquid mobile phases (see Chapter 9). The range of available detectors for SFC is considered one of its strengths. 

Figure 7.10 Typical optical arrangements employed for detection of (a) vapour phase (b) liquid phase and (c) solid chromatographic phases. After White [167], Reprinted from R. White (ed.), Chromatography/Fourier Transform Infrared Spectroscopy and Its Applications Marcel Dekker Inc., New York, NY (1990), by courtesy of Marcel Dekker Inc.

A rate enhancement effect due to secondary nucleation has been identified in the solution-mediated transformation of the 7-phase of (i)-glutamic acid to its / -phase [82]. In this study, the kinetics of the polymorphic transition were studied using optical microscopy combined with Fourier transform infrared, Raman, and ultraviolet absorption spectroscopies. The crystallization process of n-hexatriacontane was investigated using micro-IR methodology, where it was confirmed that single... 

Varenne, A., Salmain, M., Brisson, C., and Jaouen, G. (1992) Transition metal carbonyl labeling of proteins. A novel approach to a solid-phase two-site immunoassay using Fourier transform infrared spectroscopy. Bioconjugate Chem. 3, 471-476. 

Transmission infrared spectra of species adsorbed on the catalyst were taken with a Digilab FTS-10M Fourier-transform infrared spectrometer, using a resolution of 4 cm-l. To improve the signal-to-noise ratio, between 10 and 100 interferograms were co-added. Spectra of the catalyst taken following reduction in H2 were subtracted from spectra taken in the presence of NO to eliminate the spectrum of the support. Because of the very short optical path through the gas in the reactor and the low NO partial pressures used in these studies, the spectrum of gas-phase NO was extremely weak and did not interfere with the observation of the spectrum of adsorbed species. 

Figure 4.5 Schematic diagram of a Fourier transform infrared (FTIR) spectrometer. Infrared radiation enters from the left and strikes a beam-splitting mirror (BS) angled such that half of the beam is directed towards a fixed mirror (Mi) and half towards a moveable mirror (M2). On reflection the beam is recombined and directed through the sample towards the detector. M2 is moved in and out by fractions of a wavelength creating a phase difference between the two beam paths. This type of device is called a Michelson interferometer.

In order to learn about the phase states adopted by LPS and lipid A, Fourier-transform infrared spectroscopy, differential scanning calorimetry, and X-ray small-angle diffraction with CuXa or synchrotron radiation have been applied. In the following section, some recent results are summarized. 

An important tool for the fast characterization of intermediates and products in solution-phase synthesis are vibrational spectroscopic techniques such as Fourier transform infrared (FTIR) or Raman spectroscopy. These concepts have also been successfully applied to solid-phase organic chemistry. A single bead often suffices to acquire vibrational spectra that allow for qualitative and quantitative analysis of reaction products,3 reaction kinetics,4 or for decoding combinatorial libraries.5... 

One of the initial spectroscopic methods applied to stationary-phase characterization was Fourier transform infrared spectroscopy (FTIR). This originated from several important studies of phase conformational order in crystalline n-alkanes conducted in the late 1960s and early 1980s by Snyder, Maroncelli, and coworkers [111-114], In this work, assignments of C—H bond wagging modes were associated with chain... 

FIGURE 5.15 Fourier transform infrared spectroscopy absorbance spectra at different temperatures for a C22 monomeric stationary-phase. (Reproduced from Sander, L.C., et al., Anal. Chem.,55, 1068, 1983. With permission.)... 

Fourier-transform infrared (FT-IR) spectroscopy and small-angle X-ray (SAXS) and neutron (SANS) scattering studies have shown the existence of a further pressure induced gel phase in DPPC bilayers." " Pressure dependent NMR studies yielded complementary information on the pressure-induced gel phases. The gel state of DPPC bilayers shows a variation in lineshapes which depend on the particular pressure and temperature. The types of lineshapes seen in a high pressure investigation of dg2-DPPC by Jonas et al. are... 

Hjorth, J., G. Ottobrini, F. Cappellani, and G. Restelli, A Fourier Transform Infrared Study of the Rate Constant of the Homogeneous Gas-Phase Reaction N20, + H20 and Determination of Absolute Infrared Band Intensities of N205 and UNO, . /. Phys. Chem., 91, 1565-1568 (1987). 

Middlebrook, A. M., L. T. Iraci, L. S. McNeill, B. G. Koehler, M. A. Wilson, O. W. Saastad, and M. A. Tolbert, Fourier Transform-Infrared Studies of Thin H2S04/H20 Films Formation, Water Uptake, and Solid-Liquid Phase Changes, J. Geophys. Res., 98, 20473-20481 (1993). 

Table 24.1 Attributes of Reversed-Phase Liquid Chromatography-Fourier Transform Infrared Systems Using Direct... 

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