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Founded implication

Two novel classes of photochromic amorphous molecular materials based on azobenzene and dithioiylediene have been created. Photochromic behavior of these materials in solution and as amorphous films has beoi elucidated. These photochromic amorphous molecular materials based on azobenzene and didiienyledirae have found implications for SRG fcnmation and dual image formation, respectively. [Pg.184]

Quantifier, i.e., 0.9 , which is one of many generalised quantifiers in observational logic. The parhcular quantifier - p employed in the above rule is called founded implication and expresses the fact that among those objects in the available data that fulfil the condihon of the mle, at least the proportion p also fulfils its consequence (in the above rule,/ = 90%). [Pg.67]

Another example of the role played by a nonradiative relaxation pathway is found in the photochemistry of octatetraene. Here, the fluorescence lifetime is found to decrease dramatically with increasing temperature [175]. This can be assigned to the opening up of an efficient nonradiative pathway back to the ground state [6]. In recent years, nonradiative relaxation pathways have been frequently implicated in organic photochemistry, and a number of articles published on this subject [4-8]. [Pg.276]

There are finer details to be extracted from such Kohonen maps that directly reflect chemical information, and have chemical significance. A more extensive discussion of the chemical implications of the mapping of the entire dataset can be found in the original publication [28]. Gearly, such a map can now be used for the assignment of a reaction to a certain reaction type. Calculating the physicochemical descriptors of a reaction allows it to be input into this trained Kohonen network. If this reaction is mapped, say, in the area of Friedel-Crafts reactions, it can safely be classified as a feasible Friedel-Qafts reaction. [Pg.196]

Ac Che limic of Knudsen screaming Che flux relacions (5.25) determine Che fluxes explicitly in terms of partial pressure gradients, but the general flux relacions (5.4) are implicic in Che fluxes and cheir solution does not have an algebraically simple explicit form for an arbitrary number of components. It is therefore important to identify the few cases in which reasonably compact explicit solutions can be obtained. For a binary mixture, simultaneous solution of the two flux equations (5.4) is straightforward, and the result is important because most experimental work on flow and diffusion in porous media has been confined to pure substances or binary mixtures. The flux vectors are found to be given by... [Pg.42]

Quantum mechanics gives a mathematical description of the behavior of electrons that has never been found to be wrong. However, the quantum mechanical equations have never been solved exactly for any chemical system other than the hydrogen atom. Thus, the entire held of computational chemistry is built around approximate solutions. Some of these solutions are very crude and others are expected to be more accurate than any experiment that has yet been conducted. There are several implications of this situation. First, computational chemists require a knowledge of each approximation being used and how accurate the results are expected to be. Second, obtaining very accurate results requires extremely powerful computers. Third, if the equations can be solved analytically, much of the work now done on supercomputers could be performed faster and more accurately on a PC. [Pg.3]

A typical SSIMS spectrum of an organic molecule adsorbed on a surface is that of thiophene on ruthenium at 95 K, shown in Eig. 3.14 (from the study of Cocco and Tatarchuk [3.28]). Exposure was 0.5 Langmuir only (i.e. 5 x 10 torr s = 37 Pa s), and the principal positive ion peaks are those from ruthenium, consisting of a series of seven isotopic peaks around 102 amu. Ruthenium-thiophene complex fragments are, however, found at ca. 186 and 160 amu each has the same complicated isotopic pattern, indicating that interaction between the metal and the thiophene occurred even at 95 K. In addition, thiophene and protonated thiophene peaks are observed at 84 and 85 amu, respectively, with the implication that no dissociation of the thiophene had occurred. The smaller masses are those of hydrocarbon fragments of different chain length. [Pg.103]

N-Nilrosoamines are reduced easily lo ihe hydrazine and, if continued, lo the amine (62). Early workers ruled out cleavage of dimeihylhydrazine as the source of dimethylamine in hydrogenation of N-nitrosodimethylamine since liule ammonia was found the letramethylietrazene was implicated in the hydrogenolysis (fSI). Palladium-on-carbon under mild conditions is used for industrial production of dialkyl hydrazines from N-nitrosoamines. [Pg.173]

The implications of a significant role for strain rate are wider than the obvious one that stress corrosion should only occur over a restricted range of strain rates. Thus, in constant load tests, since cracks will continue to propagate only if their rate of advancement is sufficient to maintain the crack-tip strain rate above the minimum rate for cracking, it is to be expected that cracks will sometimes stop propagating, particularly below the threshold stress. Such non-propagating cracks are indeed observed below the thres-hold . Moreover, in constant-load or constant-strain tests, the strain rate diminishes with time after loading, by creep exhaustion if the stress remains sensibly constant, and it is found that the stress-corrosion results are sensitive to the relative times at which the stress and electrochemical... [Pg.1168]

Fredkin points out that even if a preferred frame, or underlying lattice, is found, its implications are in one sense only philosophical the integrity of the theory of relativity remains intact, it is only our philosophical perspective that changes. Similarly, if a deterministic RUCA-like rule is the basis of the real physics, it does not mean that we should all throw away our quantum mechanics texts. On the other, if the finite nature hypothesis is correct and a RUCA-like rule exists and can be found, it should in principle be able to supply us with values of all of the fundamental constants of physics. [Pg.668]

The excellent agreement between the TSC and P1A results has two implications. First, since the TSC method probes the product of mobility and carrier density, while the P1A probes only the carrier density, there seems to be no dominant influence of temperature on the carrier mobility. This was also found in other conjugated polymers like /ra/ry-polyacetylene [19, 36]. Second, photoconductivity (observed via the thermal release of photoexcited and trapped earners) and photo-induced absorption probe the same charged entity [36, 37J. [Pg.468]

High concentrations of KOP have been found in the cerebral cortex and hypothalamus KOP is also present in the gastrointestinal tract, in immune cells as well as in other peripheral tissues. KOPs have been implicated in the regulation of nociception, diuresis, feeding, neuroendocrine and immune system functions [2]. [Pg.905]


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See also in sourсe #XX -- [ Pg.67 ]




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