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Forward definition

The simplest kinetics to assume would be a one-step reaction from an organometallic compound to metallic deposit, i.e. the A to B first order reaction. This is essentially the approach used by Sato et al [1], which led to a straight forward definition of the Thiele modulus and the pattern of metal deposition as the fantiliar... [Pg.334]

Security for the signer will be defined in two ways. The reason is that previous definitions avoided the concept of probabilistic interactive functions in favour of better-known notions. (This could originally be done because only simple versions of key generation were considered.) Now it is simpler to make a forward definition that deals explicitly with an interactive attacker strategy that carries out authentications and one dispute. This section contains such a forward definition. The backward definition from previous publications and a proof that it is slightly (and unnecessarily) stronger than the forward definition are presented in Section 7.2.1. Nevertheless, some of the later sections are based on the backward definition. [Pg.172]

The backward definition of the security for the signer and the proof that it is slightly stronger than the forward definition. [Pg.175]

Note that these forgers are special cases of those considered with the security for the signer. In the case with several risk bearers, let B denote the combination of B and O. Hence the definition of unforgeability deals with the same probabilities PB,F,par the forward definition of the security for the signer. [Pg.181]

Straight-forward definitions of transitions are available only for the first-order and glass transitions. The basic definitions of both transitions are given in Sect. 2.5 and experimental information is summarized in Sects. 5.4-6. As the dictionary definition of Fig. 2.115 indicates, even subtle changes maybe, and have been, called transitions. The observation of gradual changes without transitions have been documented with some examples in Sect. 5.5 (see Fig. 2.108 and 5.143). The definition of the order of thermodynamic transitions, finally is discussed with Fig. 2.119 [2]. [Pg.592]

The described method can generate a first-order backward or a first-order forward difference scheme depending whether 0 = 0 or 0 = 1 is used. For 9 = 0.5, the method yields a second order accurate central difference scheme, however, other considerations such as the stability of numerical calculations should be taken into account. Stability analysis for this class of time stepping methods can only be carried out for simple cases where the coefficient matrix in Equation (2.106) is symmetric and positive-definite (i.e. self-adjoint problems Zienkiewicz and Taylor, 1994). Obviously, this will not be the case in most types of engineering flow problems. In practice, therefore, selection of appropriate values of 6 and time increment At is usually based on trial and error. Factors such as the nature of non-linearity of physical parameters and the type of elements used in the spatial discretization usually influence the selection of the values of 0 and At in a problem. [Pg.66]

The term mesoionic was suggested originally to describe compounds of the sydnone (129) or sydnone imine (130) type (49JCS307, 50JCS1542). Since then this term has been applied somewhat indiscriminately to a variety of heterocyclic molecules which can be represented formally as zwitterions. The original, rather restrictive definition put forward by Baker and Ollis (55CI(L)910) was later made even more so by Ollis and Ramsden (76AHC(19)1), and it is this most recent definition which now appears to be the most useful. [Pg.34]

This must be a clear and definite intersection and not the situation represented in Figure 12-146 for a forward bladed fan system. Note that the limit curve parallels the static curve and has a very poor long tangential intersection. The... [Pg.568]

The result is that while there is, in DM, something that might be called an information cone centered at each site, it is not really what we usually think of as a relativistic, light cone, for wliidi we can point to interior points and definitely say they arc causally related and know for sure that points outside of each other s light cones are completely independent. In DM it is simply false to say that only those events inside the information cone of the past can influence a present event the information cone can well consist of lights cones stretching into all directions, forward and back in time. [Pg.668]

Thus, two interpretations based on two different concepts of the effect of temperature on dipole orientation have been put forward. The two views clash with each other on physical as well as chemical grounds. However, the view based on the correlation of Fig. 25 introduces chemical concepts that are absent in the other, which ignores some definite facts. For instance, although a value for dEa=0/dT is not available for Ga, the temperature coefficient of C is apparently small.905 Ga is universally recognized as a strongly hydrophilic metal. Therefore, according to the simple model of up-and-down dipoles, the effect of temperature should be major, which is in fact not the case. [Pg.185]

The solution of system (6.56) is a very complicated mathematical problem it definitely needs numerical calculations on some stages of processing. At least two successful attempts to overcome these difficulties are well known in the literature. The first method was put forward by Sack and expresses the solution through a continuous fraction. The second was proposed by Fixman and Rider [29], and deals with a kinetic... [Pg.212]

Having discussed some explanations for the continued difficulty with defining mentoring, let us now take a look at a sample of definitions that have been put forward ... [Pg.8]

This definition for reaction order is directly meaningful only for irreversible or forward reactions that have rate expressions in the form of Equation (1.20). Components A, B,... are consumed by the reaction and have negative stoichiometric coefficients so that m = —va, n = —vb,. .. are positive. For elementary reactions, m and n must be integers of 2 or less and must sum to 2 or less. [Pg.8]

This observation is the first part of the cancellation puzzle [20, 21, 27, 29]. We know from Section lll.B that we should be able to solve it directly by applying Eq. (19), which will separate out the contributions to the DCS made by the 1-TS and 2-TS reaction paths. That this is true is shown by Fig. 9(b). It is apparent that the main backward concentration of the scattering comes entirely from the 1-TS paths. This is not a surprise, since, by definition, the direct abstraction mechanism mentioned only involves one TS. What is perhaps surprising is that the small lumps in the forward direction, which might have been mistaken for numerical noise, are in fact the products of the 2-TS paths. Since the 1-TS and 2-TS paths scatter their products into completely different regions of space, there is no interference between the amplitudes f (0) and hence no GP effects. [Pg.24]

Because the sense, or sign, of chiral asymmetry in the forward-backward electron scattering asymmetry depends on the helicity of the photon and of the molecule, it is essential that these variables are properly specified in any study to permit meaningful comparisons to be made. Discussing and comparing quantitative asymmetry factors, y [Eq. (8)] and dichroism [Eq. (9)] likewise requires agreement on the convention adopted in the definition of these terms. [Pg.324]

If there is a difference between the measured and calculated fields, all parameters of the first approximation or some of them are changed in such a way that a better fit to these fields is achieved. Thus, we obtain a second approximation of mass distribution. Of course, in those cases when even the new set of parameters does not provide a satisfactory match of these fields, this process of calculation has to be continued. As we see from this process, every step of the interpretation requires application of Newton s law. Let us recall that this procedure, based on the use of Newton s law, is often called the solution of the forward problem of the field of attraction, and by definition we have... [Pg.220]

The phenomenal growth of the World Wide Web and Internet has revolutionized the delivery of text and image-based information. All signs point to the idea that this will be the definitive technology for the foreseeable future. The rate of change in computer capabilities will pull us all forward. Some of us may not be in the position to drive such changes but merely will be able to follow. One sees acronyms such as CADDY, PDF, HRML, and XML, but what exactly do they mean How would an electronic submission function What would it look like What are the basic pieces, or building blocks, of an electronic submission ... [Pg.1066]

The underlined values in the sample data fit the definition of baseline. You can see how the last non-missing value should be carried forward. The following SAS code selects those proper baseline values. [Pg.87]

TOF spectra of the H atom products have been measured at 18 laboratory angles (from 117.5° to —50° at about 10° intervals). Figure 19 shows a typical TOF spectrum at the laboratory (LAB) angle of —50° (forward direction). By definition, the forwardness and backwardness of the OH product is defined here relative to the 0(7D) beam direction. The TOF spectrum in Fig. 19 consists of a lot of sharp structures. All these sharp structures clearly correspond to individual rotational states of the OH product, indicating that these TOF spectra have indeed achieved rotational state resolution for the 0(1D)+H2 — OH+H reaction. By converting these TOF spectra from the laboratory (LAB) frame to the center-of-mass (CM) frame... [Pg.120]

Time-of-fhght spectra of the D atom products have been measured at many laboratory angles at both collision energies. Translational energy distributions can be derived by direct conversion of these TOF spectra. For the experiment carried out at 2.0 kcal/mol, Fig. 28(a) shows the total product angular distribution from 0 = —60° to 117.5°, which correspond to the forward (—60°), the sideward (30°) and the backward (117.5°) scattering directions. The direction of the D2 beam is at 0 = 0°, while the direction of the 0(XD) beam is at 0/. 90°. By definition, the forwardness and back-... [Pg.133]


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See also in sourсe #XX -- [ Pg.121 ]




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