Forced convection Levich equation

In filtration, the particle-collector interaction is taken as the sum of the London-van der Waals and double layer interactions, i.e. the Deijagin-Landau-Verwey-Overbeek (DLVO) theory. In most cases, the London-van der Waals force is attractive. The double layer interaction, on the other hand, may be repulsive or attractive depending on whether the surface of the particle and the collector bear like or opposite charges. The range and distance dependence is also different. The DLVO theory was later extended with contributions from the Born repulsion, hydration (structural) forces, hydrophobic interactions and steric hindrance originating from adsorbed macromolecules or polymers. Because no analytical solutions exist for the full convective diffusion equation, a number of approximations were devised (e.g., Smoluchowski-Levich approximation, and the surface force boundary layer approximation) to solve the equations in an approximate way, using analytical methods. 

When van der Waals and double-layer forces are effective over a distance which is short compared to the diffusion boundary-layer thickness, the rate of deposition may be calculated by lumping the effect of the particle-collector interactions into a boundary condition on the usual convective-diffusion equation. This condition takes the form of a first-order irreversible reaction (10, 11). Using this boundary condition to eliminate the solute concentration next to the disk from Levich s (12) boundaiy-kyersolution of the convective-diffusion equation for a rotating disk, one obtains... 

Impedance may also be studied in the case of forced diffusion. The most important example of such a technique is a rotating disk electrode (RDE). In a RDE conditions a steady state is obtained and the observed current is time independent, leading to the Levich equation [17]. The general diffusion-convection equation written in cylindrical coordinates y, r, and q> is [17]... 

Gibaldi et al. [45] postulated that convective forces may be present in the GI tract during in vivo dissolution. This study took advantage of the well-defined hydrodynamics of the rotating disk, incorporating the solutions for the velocity profile and transport equations of Cochran [50] and Levich [51] to obtain... 

Two limiting situations may be identified r (1) the rate constant K is very small compared to aD, hence the process occurring in the interaction forces boundary layer controls the deposition rate, and (2) the rate constant K is very large hence the convective diffusion is the controlling factor. The first limiting case was treated by Hull and Kitchener (except for the variation of the diffusion coefficient) while the second was treated by Levich. In the present paper an equation is established which is valid for all values of the rate constant thus also incorporating both limiting situations. 

Fig. 3- Cose 1. Sherwood numbers computed for the convective-diffusion of particles of finite sine to the surface of a spherical collector by neglecting interaction forces. The dashed line is the Levich-LighthilJ equation (19) which is valid when a diffusion boundary-layer exists and the particles are infinitesimal.

Fig. 6. Sherwood numbers computed for the transport of finite particles to a spherical collector under the combined action of convective-diffusion and London forces. Values of the aspect ratio are (a) ft - 104, (b) ft — 105, (c) ft =- 10s, and (d) ft = 10. For each aspect ratio, the value of A/kT was taken (upper curves to lower curves) as ID2, 1, 10 2 and 10 4. Dashed lines represent the Levich-Lighthill equation (19), while the dotted curves represent Sherwood numbers deduced from Figure 4 which ignores the transport from diffusion.

In more complicated models both equations have to be generalised by coupling surface and bulk convective diffusion and hydrodynamics. The situation is finely balanced since the motion of the surface has an effect on the formation of the dynamic adsorption layer, and vice versa. Adsorption increases in the direction of the liquid motion while the surface tension decreases. This results in the appearance of forces directed against the flow and retards the surface motion. Thus, the dynamic layer theory should be based on the common solution of the diffusion equation, which takes into account the effect of surface motion on adsorption-desorption processes and of hydrodynamics equations combined with the effect of adsorption layers on the liquid interfacial motion (Levich 1962). 

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