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Fluorine, reaction with magnesium

Write a balanced equation for the reaction that occurs in each of the following cases (a) Chlorine reacts with water, (b) Bariitm metal is heated in an atmosphere of hydrogen gas. (c) Lithiirm reacts with sulfur, (d) Fluorine reacts with magnesium metal. [Pg.294]

The synthesis of new perfluoroaliphatic compounds of magnesium and lithium has continued, although at a reduced effort Perfluoroorganometallics offer a variety of reactions with numerous substrates, which contributed to the development of the chemistry of fluorine containing compounds... [Pg.652]

Hydrofluoric acids - [ALUMINUMAND ALUMINUM ALLOYS] (Vol 2) - [ALUMINUMCOMPOUNDS - INTRODUCTION] (Vol2) - [FINECHEMICALS - STANDARDS] (Vol 10) -effect on glass [GLASS] (Vol 12) -magnesium reaction [MAGNESIUM AND MAGNESIUM ALLOYS] (Vol 15) -reaction with fluorine [FLUORINE] (Vol 11) - [COAL] (Vol 6)... [Pg.489]

Ref 93). Extreme caution should be used in reducing any fluorinated compound with LiAlH4. Violent reactions have been observed with two different fluoro compounds (Refs 76 95). Excess trimethyl amine, NMes, reacts with an ethereal /solution of LiAlH4 in vacuo at -SO t to form a white addition compound which is slightly soluble in ether, insoluble in benzene, and spontaneously flammable in air (Ref 98a) Magnesium perchlorate may be used as a drying... [Pg.431]

In light of your answers to Problem 6.94, which compound is more likely to form in the reaction of magnesium with fluorine, MgF2 or MgF ... [Pg.240]

Explosive reaction with chlorosulfuric acid, hydroiodic acid, magnesium perchlorate, chromyl chloride. Forms sensitive explosive mixtures with metal halogenates (e.g., chlorates, bromates, or iodates of barium, calcium, magnesium, potassium, sodium, zinc), ammonium nitrate, mercury(1) nitrate, silver nitrate, sodium nitrate, potassium permanganate. Violent reaction or ignition with alkalies + heat, fluorine, chlorine, liquid bromine, antimony pentachloride. Reacts with hot alkalies or hydroiodic acid to form... [Pg.1118]

DOT CLASSIFICATION 8 Label Corrosive SAFETY PROFILE Poison by inhalation. Moderately toxic by ingestion. A severe eye, skin, and mucous membrane irritant. Corrosive to body tissues. Flammable by chemical reaction. Explosive reaction with chlorine dioxide + chlorine, sodium, urea + heat. Reacts to form explosive products with carbamates, 3 -methyl-2-nitroben2anilide (product explodes on contact with air). Ignites on contact with fluorine. Reacts violently with moisture, CIO3, hydroxyl-amine, magnesium oxide, nitrobenzene, phosphorus(III) oxide, K. To fight fire, use CO2, dry chemical. Incompatible with aluminum, chlorine dioxide, chlorine. [Pg.1121]

This reaction liberated 17.3 MeV, the mass afterwards being 0.0186 AMU less than before. Beryllium, fluorine, sodium and magnesium provide nuclides which undergo proton-induced reactions. Nitrogen-14 yields carbon-11, a positron-emitter with a half-life of twenty minutes. [Pg.21]

Consider the reaction of magnesium with fluorine to form magnesium fluoride ... [Pg.144]

The range of possible fluorination reactions on electron-rich double bonds, eno-lates, and enol ethers, with Selectfluor (F-TEDA-BF4) as example, is depicted in Scheme 2.88. Yields from the fluorination of unstabilized carbanions, for example phenyl magnesium bromide, are usually relatively low, mostly because of competing oxidation side-reactions. [Pg.78]

Reaction of trifluoromethyl vinyl ketones with magnesium/MesSiCl leads to a di-fluoro analog of Danishefsky s diene (24) [34] (Scheme 2.200) which is a useful building block for synthesis of fluorinated heterocycles [35],... [Pg.164]

The camphorylsulfinylimine (146) with lithium aliuninum hydride is reduced to the (2/ )-10,2-bomane sultam (147) (R = Y = H), and reaction with methyl magnesium iodide in the presence of copper(I) chloride gives the methyl analog (147) (R = Me, Y = H) <88TL6087>. The fluorination of... [Pg.349]

ACID AMMONIUM CARBONATE or ACID AMMONIUM CARBONATE, MONO AMMONIUM SALT (1066-33-7) CHjOj HjN NH4HCO3 Noncomustible solid (Fire Rating 1). Violent reaction with strong acids, forming carbon dioxide. Reacts with strong bases, forming ammonia. In temperatures above 140°F/49°C, ammonia and carbon dioxide fumes are formed. Reacts with fluorine, magnesium, sodium hypochlorite. [Pg.24]


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See also in sourсe #XX -- [ Pg.4 ]




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Fluorination with

Fluorine reaction with

Fluorine reactions

Magnesium reactions

Magnesium reactions with

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