Flowsheets scrubbing

The solution involves the use of two water substreams for scrubbing at 293 and 298 K. The first coolant is employed to undertake the cooling duty. Several conceptual flowsheets can be developed to implement this solution. Figures 9.18a and b illustrate such configurations. The developed mass exchanger is composed two sections. The top section employs Si,3 to reduce the ammonia composition in the gas from 0.13% to 0.10% and operates at an average water temperature of 293 K. In Fig. 9.18a, temperature is reduced by indirect contact cooling of the... 

The final flowsheet that was developed for chromium removal is shown in Figure 25.13. The concentrate was scrubbed with alkaline followed by desliming. The deslimed concentrate was subjected to chromium flotation followed by a single cleaning stage. 

The desired separation and purification specifications are easily obtained by successive extraction-scrubbing-stripping steps. Flowsheet design is very flexible. 

Minor experimental modifications, such as the use of hydrophilic complex-ants to ease the scrubbing and stripping of the loaded solvents and simplify the flowsheets. 

The second flowsheet was therefore implemented in 24 stages (Figure 3.13) (177). This time, the An(III) + Ln(III) product solution contained only 0.66% Sr and 1.31% Mo. However, the large amounts of oxalic acid (up to 0.4 M) introduced in the feed and scrubbing solutions to avoid Zr extraction led to partial precipitation of An(III) and Ln(III) oxalates in the low acidity conditions of the stripping section. 

Although solvent samples have been observed for approximately one year without any solids formation, work was completed to define a new solvent composition that was thermodynamically stable with respect to solids formation and to expand the operating temperature with respect to third-phase formation.109 Chemical and physical data as a function of solvent component concentrations were collected. The data included BC6 solubility cesium distribution ratio under extraction, scrub, and strip conditions flowsheet robustness temperature range of third-phase formation dispersion numbers for the solvent against waste simulant, scrub and strip acids, and sodium hydroxide wash solutions solvent density viscosity and surface and interfacial tension. These data were mapped against a set of predefined performance criteria. The composition of 0.007 M BC6, 0.75 M l-(2,2,3,3-tetrafluoropropoxy)-3-(4-.sw-butylphenoxy)-2-propanol, and 0.003 M TOA in the diluent Isopar L provided the best match between the measured properties and the performance criteria. 

A solvent-extraction flowsheet is broken down into sections such as extraction, scrub, and strip. For each section, one or more component in a process fluid must be moved from one phase to the other phase with a specified degree of completeness. The first design problem is to determine the number of stages for each section to accomplish the required component transfer. With the well-defined stages of the centrifugal contactor, the following extraction factor (E) can be used to estimate the number of stages required ... 

Figure 2. Chemistry occurring in three sections of a simple flowsheet in solvent extraction using CSSX as an example. In the extraction step, essentially all of the Cs+ and a minor fraction of the K+ ions in the waste are extracted (i.e., M+ = Cs+ or K+). The K+ ions are removed in scrubbing as shown, while the calixcrown-Cs+ complex effectively remains in the solvent so that a pure cesium nitrate product is obtained on stripping.

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