Films gloss

In addition to polyamide, lamination inks ordinarily contain modifiers such as polyketone resin, plasticizer, and wax to impart specific properties such as block resistance and increased bond strength. Because laminating inks are usually reverse-side printed and end-up sandwiched between films, gloss is not a primary requirement. Water-base laminating inks that will meet the U.S. EPA emission requirements and have the correct functional properties are currently under development. 

Pigments can also influence other coating properties (e.g., film gloss) as a result of complex interactions between the pigment, binder, and solvent, and the method of application. 

Optical Properties Exact Plastomers exhibit very high levels of film gloss, with low haze in tough films used for fresh and processed meat, poultry wraps, or pouch containers. " ... 

Alkyd chemistry lends itself to further modification beyond choice of polyol, dibasic acid, and drying oil. Vinyl-modified alkyds, for example, are produced for more durable and quicker drying films, although with some sacrifice in crosslinking rate and consequent development of solvent resistance. Styrene, vinyl toluene, and methyl methacrylate are the most commonly used modifiers. In the presence of a free radical initiator, vinyl polymer will graft onto the alkyd. Tack-free time (i.e. a surface-dry film) may be reduced from 4 to 6 hoius for an unmodified alkyd to 1 hour in styrenated form. Acrylics, silicones, phenolic resins, and natural resins are likewise used to tailor film gloss, flexibility, durability, and drying time for certain applications. 

No reliable test methods for measuring the surface gloss of film laminates have, so far, been established. As such, the assessment of surface film gloss is best carried out visually. Evident graying is an indication of tiny air bubbles between board and film. These may be caused by inadequate application of adhesives, insufficient drying, or coalescence of the adhesive during lamination. Optical microscopy has also proven useful in confirming defect types in laminates. 

The process can be used to recover scrap or low quaUty resins by using them as the core layer, and using outer layers of virgin resins designed for the specific functional needs of the product such as sHp or gloss and appearance. The inner core may be a foamed resin with surface layers of supedor finish resins. Coextmded films often eliminate the need for cosdy lamination processes. 

Whereas semigloss paints can use only one extender, dat paints, especially interior, can use combinations of three or more. Gloss paints typically do not use extenders, which decrease gloss. As a result, gloss paints lack the hardening effect of extenders and must rely on harder binders for adequate durabihty. Other types of extenders used in paints can have functional properties such as corrosion resistance, mildew resistance, and film-hardening effects. Thek functional properties result from thek reactive nature in the paint film. Zinc oxide is an example of a functional extender that contributes to these properties in a paint film. 

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