Filament control

Figure 9. Nylon filament control. Surface is clean and undamaged. Magnification ca. 1370X-...

CIO2 is not recommended for freshwater treatment. This is based on field experience, and probable causes include lack of persistence (flashing off ) and poor filamentous control. However, it is commonly used for process water treatment especially if the pulp mill is supplying it cheap. 

The coin-tap test is a widely used teclinique on thin filament winded beams for detection of disbonded and delaminated areas. However, since the sensitivity of this teclinique depends not only on the operator but also on the thickness of the inspected component, the coin-tap testing technique is most sensitive to defects positioned near the surface of the laminate. Therefore, it was decided to constructed a new scaimer for automated ultrasonic inspection of filament winded beams. A complete test rig illustrated in figure 6 was constructed in order to reduce the scanning time. While the beam rotates the probe is moved from one end to the other of the beam. When the scarming is complete it is saved on diskette and can then be evaluated on a PC. The scanner is controlled by the P-scan system, which enables the results to be presented in three dimensions (Top, Side and End view). 

The previous discussion demonstrates that measurement of precise isotope ratios requires a substantial amount of operator experience, particularly with samples that have not been examined previously. A choice of filament metal must be made, the preparation of the sample on the filament surface is important (particularly when activators are used), and the rate of evaporation (and therefore temperature control) may be crucial. Despite these challenges, this method of surface ionization is a useful technique for measuring precise isotope ratios for multiple isotopes. Other chapters in this book discuss practical details and applications. 

The heated polymer solution emerges as filaments from the spinneret into a column of warm air. Instantaneous loss of solvent from the surface of the filament causes a soHd skin to form over the stiU-Hquid interior. As the filament is heated by the warm air, more solvent evaporates. More than 80% of the solvent can be removed during a brief residence time of less than 1 s in the hot air column. The air column or cabinet height is 2—8 m, depending on the extent of drying required and the extmsion speed. The air flow may be concurrent or countercurrent to the direction of fiber movement. The fiber properties are contingent on the solvent-removal rate, and precise air flow and temperature control are necessary. 

Process. Any standard precursor material can be used, but the preferred material is wet spun Courtaulds special acrylic fiber (SAF), oxidized by RK Carbon Fibers Co. to form 6K Panox B oxidized polyacrylonitrile (PAN) fiber (OPF). This OPF is treated ia a nitrogen atmosphere at 450—750°C, preferably 525—595°C, to give fibers having between 69—70% C, 19% N density less than 2.5 g/mL and a specific resistivity under 10 ° ohm-cm. If crimp is desired, the fibers are first knit iato a sock before heat treating and then de-knit. Controlled carbonization of precursor filaments results ia a linear Dow fiber (LDF), whereas controlled carbonization of knit precursor fibers results ia a curly carbonaceous fiber (EDF). At higher carbonizing temperatures of 1000—1400°C the fibers become electrically conductive (22). 

Additional complications can occur if the mode of deformation of the material in the process differs from that of the measurement method. Most fluid rheology measurements are made under shear. If the material is extended, broken into droplets, or drawn into filaments, the extensional viscosity may be a more appropriate quantity for correlation with performance. This is the case in the parting nip of a roUer in which filamenting paint can cause roUer spatter if the extensional viscosity exceeds certain limits (109). In a number of cases shear stress is the key factor rather than shear rate, and controlled stress measurements are necessary. 

Extrusion Resins. Extmsion of VDC—VC copolymers is the main fabrication technique for filaments, films, rods, and tubing or pipe, and involves the same concerns for thermal degradation, streamlined flow, and noncatalytic materials of constmction as described for injection-molding resins (84,122). The plastic leaves the extmsion die in a completely amorphous condition and is maintained in this state by quenching in a water bath to about 10°C, thereby inhibiting recrystallization. In this state, the plastic is soft, weak, and pHable. If it is allowed to remain at room temperature, it hardens gradually and recrystallizes partially at a slow rate with a random crystal arrangement. Heat treatment can be used to recrystallize at controlled rates. 

Plug dow is apphcable for readily degradable wastewaters subject to filamentous bulking. Upstream controls are required to avoid shock loadings. 

The selector process is apphcable for readily degradable wastewaters it also requires upstream controls. In a selector, degradable organics are removed by the doc formers by biosorption and therefore are not available as a food source for the filaments. 

The sequencing batch reactor (SBR) or intermittent process is a combination of complete mix and plug dow, and usually controls filamentous bulking. The nature of the process eliminates the need for an external clarifier. 

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