Ferrites high-temperature alloys

Use Nuclear technology, iron and other alloys, deoxidizer for vanadium and other nonferrous metals, microwave ferrites, coating on high-temperature alloys, special semiconductors. 

M. Rudy, 1. Jung, G. Sauthoff. Ferritic Fe-Ni-Al Alloys for High Temperature Applications. In J. B. Marriott, M. Merz, J. Nihoul et al. High Temperature Alloys - Their Exploitable Potential. Elsevier Appl. Sci., London (1987) 29-37. 

Precipitation Hardening. With the exception of ferritic steels, which can be hardened either by the martensitic transformation or by eutectoid decomposition, most heat-treatable alloys are of the precipitation-hardening type. During heat treatment of these alloys, a controlled dispersion of submicroscopic particles is formed in the microstmeture. The final properties depend on the manner in which particles are dispersed, and on particle size and stabiUty. Because precipitation-hardening alloys can retain strength at temperatures above those at which martensitic steels become unstable, these alloys become an important, in fact pre-eminent, class of high temperature materials. 

Ferritic stainless steels depend on chromium for high temperature corrosion resistance. A Cr202 scale may form on an alloy above 600°C when the chromium content is ca 13 wt % (36,37). This scale has excellent protective properties and occurs iu the form of a very thin layer containing up to 2 wt % iron. At chromium contents above 19 wt % the metal loss owiag to oxidation at 950°C is quite small. Such alloys also are quite resistant to attack by water vapor at 600°C (38). Isothermal oxidation resistance for some ferritic stainless steels has been reported after 10,000 h at 815°C (39). Grades 410 and 430, with 11.5—13.5 wt % Cr and 14—18 wt % Cr, respectively, behaved significandy better than type 409 which has a chromium content of 11 wt %. 

A good summary of the behavior of steels in high temperature steam is available (45). Calculated scale thickness for 10 years of exposure of ferritic steels in 593°C and 13.8 MPa (2000 psi) superheated steam is about 0.64 mm for 5 Cr—0.5 Mo steels, and 1 mm for 2.25 Cr—1 Mo steels. Steam pressure does not seem to have much influence. The steels form duplex layer scales of a uniform thickness. Scales on austenitic steels in the same test also form two layers but were irregular. Generally, the higher the alloy content, the thinner the oxide scale. Excessively thick oxide scale can exfoHate and be prone to under-the-scale concentration of corrodents and corrosion. ExfoHated scale can cause soHd particle erosion of the downstream equipment and clogging. Thick scale on boiler tubes impairs heat transfer and causes an increase in metal temperature. 

The ferritic chromium steels (chromium is the principal alloying element) are the most economical for very lightly loaded high-temperature situations. However, they are inadequate when creep must be accounted for. Austenitic steels are often recommended for such conditions. The 17% chromium alloys (Type 430) resist scaling up to 800°C and 25% alloy (Type 446) up to llOO C [21]. 

Compared with ferritic carbon and low-alloy steels, relatively little information is available in the literature concerning stainless steels or nickel-base alloys. From the preceding section concerning low-alloy steels in high temperature aqueous environments, where environmental effects depend critically on water chemistry and dissolution and repassivation kinetics when protective oxide films are ruptured, it can be anticipated that this factor would be of even more importance for more highly alloyed corrosion-resistant materials. 

A 335 Seamless Ferritic Alloy-Steel Pipe for High-Temperature Service [Note (2)]... 

A 369 Carbon and Ferritic Alloy Steel Forged and Bored Pipe for High-Temperature Service... 

For high temperature SOFCs, a conventional commercial alloy cannot be used as the interconnector because they are easily oxidized under a high temperature oxidizing atmosphere. Therefore presently, special rare metals or doped-LaCr03 are used as the interconnector. For low temperature SOFCs, a commercial alloy can be used as the interconnector and thus, various alloys are considered as the interconnector. Austenite stainless steels have a high TEC in comparison to YSZ, and only ferritic stainless steels are considered as a candidate for the interconnector. 

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