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Fast EIS

Kit name Egg Veratox for egg FASTKIT ELISA Ver. II Egg FASPEK Egg RADASCREEN FAST Ei/Egg Egg BIOKITS EGG... [Pg.325]

The hydrogen should effuse out four times as fast eis the oxygen. [Pg.227]

Chromatographic Characterization of TTXs. The vast majority of reports have identified TTX and anhydro-TTX in bacterial cultures using HPLC, TLC, and GC-MS. Yasumoto et al. (30) showed that TTX-like substances extracted from a Pseudomonas sp. culture could bind to activated charcoal at pH 5.5 and be eluted with 20% ethanol in 1% acetic acid. In addition, HPLC analysis demonstrated TTX and anhydro-TTX-like fluorophors following strong base treatment. These compounds migrated on silica gel comparably to TTX and anhydro-TTX. Furthermore, when analyzed by electron ionization (EI)-MS and fast atom... [Pg.82]

Montaudo and co-workers have used direct pyrolysis mass spectrometry (DPMS) to analyse the high-temperature (>500°C) pyrolysis compounds evolved from several condensation polymers, including poly(bisphenol-A-carbonate) [69], poly(ether sulfone) (PES) and poly(phenylene oxide) (PPO) [72] and poly(phenylene sulfide) (PPS) [73]. Additionally, in order to obtain data on the involatile charred residue formed during the isothermal pyrolysis process, the pyrolysis residue was subjected to aminolysis, and then the aminolyzed residue analysed using fast atom bombardment (FAB) MS. During the DPMS measurements, EI-MS scans were made every 3 s continuously over the mass range 10-1,000 Da with an interscan time of 3 s. [Pg.423]

MeV/amu Au53+ ions on helium, neon, and argon targets. These studies are also discussed in Section III. They show that the prediction of ultralow- and low-energy electrons in fast ion-induced ionization using the CDW-EIS model depend on the details of the target potential. [Pg.313]

Competitive inhibition involves (only) the substrate (S) and the inhibitor (I) competing for one type of site on the enzyme (E), in fast, reversible steps, followed by the slow decomposition of the complex ES to form product (P) the complex El is assumed to be inactive. The fact that there is only one type of binding site on the enzyme implies that a ternary complex EIS cannot be formed. [Pg.273]

It was also found that the CDW-EIS theory was successful in describing the experimental results for longitudinal momentum distributions of fast highly charged projectile ions by neutral target atoms produced with reaction microscopy technique. ... [Pg.311]

The main aim of this paper is to review the CDW-EIS model used commonly in the decription of heavy particle collisions. A theoretical description of the CDW-EIS model is presented in section 2. In section 3 we discuss the suitablity of the CDW-EIS model to study the characteristics of ultra-low and low energy electrons ejected from fast heavy-ion helium, neon and argon atom collisions. There are some distinct characteristics based on two-centre electron emission that may be identified in this spectrum. This study also allows us to examine the dependence of the cross sections on the initial state wave function of multi-electron targets and as such is important in aiding our understanding of the ionization process. [Pg.311]

Recently Schulz et aland Fischer et al have had some difficulty in applying the CDW-EIS theory successfully for fully differential cross sections in fast ion-atom collisions at large perturbations. These ionization cross sections are expected to be sensitive to the quality of the target wave function and therefore accurate wave functions are needed to calculate these cross sections. Thus one purpose of this paper is to address this problem theoretically by re-examining the CDW-EIS model and the assumptions on which it is based. We will explore this by employing different potentials to represent the interaction between the ionized electron, projectile ion and residual target ion. For other recent work carried out on fully differential cross sections see and references therein. This discussion is presented in section 4. [Pg.311]

Particle beam is especially useful in identifying unknown compounds, despite its limitations with respect to the quantification and its lack of sensitivity at trace levels (51). Particle beam-MS is generally carried out in the positive El, because EI-MS provides very reproducible mass spectra, and a wide variety of mass spectra libraries, containing up to 130,000 entries, are available for fast identification. Chemical ionization with positive (PCI) or negative (NCI) ion de-... [Pg.748]

When optically inactive polystyrene was used as adsorbent, no difference in the relative peak intensity at m/z 288 to 286 was detected. Moreover, in the resolution of (RS)-1,1 -bi-2-naphthol and (if5)-l,l,-bi-2-naphthol-rf2 on the CSP, no isotope effect was observed. These findings indicate that the difference in EI-MS spectra is due to the difference in desorption between the enantiomers from the chiral adsorbent tris(5-f uoro-2-methylphenylcarbamate). This method can be used to discriminate the chirality of other enantiomers of small molecules if they show peaks in their EI-MS spectra in the presence of chiral polymers. Similar chiral recognition was detected by negative ion fast-atom bombardment mass spectrometry [34],... [Pg.40]


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