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Polarization probe.s. Polarization methods other than LPR are also of use in process control and corrosion analysis, but only a few systems are offered commercially. These systems use such polarization techniques as galvanodynamic or potentiodynamic, potentiostatic or galvanostatic, potentiostaircase or galvanostaircase, or cyclic polarization methods. Some systems involving these techniques are, in fact, used regularly in processing plants. These methods are used in situ or... [Pg.2439]

Unfortunately, some authors describing their work as Bayesian inference or Bayesian statistics have not, in fact, used Bayesian statistics rather, they used Bayes rule to calculate various probabilities of one observed variable conditional upon another. Their work turns out to comprise derivations of informative prior distributions, usually of the form piQi, 02,..., 0 1 = which is interpreted as the posterior distribution... [Pg.338]

This solution will dissolve cellulose which can be reprecipitated by acidification, a fact used in one of the processes for producing rayon. [Pg.1191]

Although azoles are commonly thought of as only yellow metal inhibitors, they are, in fact, used for corrosion inhibition in a wider range of metals such as steel and aluminum. They also are often incorporated in molybdate-based programs to both provide some synergism and reduce the level of molybdate required. Azoles also are employed in many types of organic-based formulations, where they improve the overall protection of steel and reduce the risk of corrosion of yellow metals due to the corrosive action of some common phosphonates. [Pg.401]

We are still years away from building molecular machines. In fact, using STM as a tool for molecular engineering has been compared to trying to build a wristwatch with a sharpened stick. [Pg.69]

Antifreezing agents for cement consist mainly of salts such as calcium chloride, magnesium chloride, sodium chloride, and soda. Calcium chloride is highly corrosive and very restricted in use. Some salts, especially potassium chloride, will affect the curing time of cement. The latter chemical is in fact used to increase the pot life of cement. Likewise, alcohol freezing-point depressants, such as ethylene glycol, can be also included in the composition [1022]. [Pg.191]

To conclusively disprove the involvement of the chromanol methide radical, the reaction of a-tocopherol with dibenzoyl peroxide was conducted in the presence of a large excess of ethyl vinyl ether used as a solvent component. If 5a-a-tocopheryl benzoate (11) was formed homolytically according to Fig. 6.6, the presence of ethyl vinyl ether should have no large influence on the product distribution. However, if (11) was formed heterolytically according to Fig. 6.9, the intermediate o-QM 3 would be readily trapped by ethyl vinyl ether in a hetero-Diels-Alder process with inverse electron demand,27 thus drastically reducing the amount of 11 formed. Exactly the latter outcome was observed experimentally. In fact, using a 10-fold excess of ethyl vinyl ether relative to a-tocopherol and azobis(isobutyronitrile) (AIBN) as radical... [Pg.171]

Looking back at the design presented for this problem in Figure 16.9, it does in fact use the minimum number of units of 7. In the next chapter, design for the minimum number of units will be addressed. [Pg.388]

Guanidines attached to a group of appropriate lipophilicity have proven to be useful antihypertensive agents, active by virtue of their peripheral sympathetic blocking activity. Debrisoguine (72) is m fact used clinically for that indication. The 7-bromo analogue (76) also shows antihypertensive... [Pg.374]

Despite the complexity of the chemical composition of the resinous materials, in a few minutes such techniques provide a mass spectral fingerprint, which highlights the compounds that are the main components in the sample. They avoid any sampling treatment before analysis. They have thus enabled diterpenoid resinous materials from Coniferae, and several triterpenoid materials to be clearly identified. In particular, the DE-MS technique is able to distinguish between different triterpenoid materials such as mastic resin, frankincense resin and birch bark tar. In fact, using PCA on DE-MS mass... [Pg.93]

The provision of a small refrigerator is attractive, but the device must be of long life (several years), very reliable and low in power consumption, weight and vibration. The alternative is to provide a store of cryogenic liquid, but the experiment then has a comparatively short lifetime. Both methods are, in fact, used. [Pg.316]

In fact, using data for 59 and 60 with the same solvent and a fortiori from the same paper45, we deduce that 60 is seemingly destabilized by 5 kJ mol 1. [Pg.84]

Of course, a minimum or maximum may exist at x even though it is not possible to demonstrate the fact using the three conditions. For example, if fix) = jc473, jc = 0 is a minimum but H(0) is not defined at jc = 0, hence condition 3 is not satisfied. [Pg.138]

Protein structures are so diverse that it is sometimes difficult to assign them unambiguously to particular structural classes. Such borderline cases are, in fact, useful in that they mandate precise definition of the structural classes. In the present context, several proteins have been called //-helical although, in a strict sense, they do not fit the definitions of //-helices or //-solenoids. For example, Perutz et al. (2002) proposed a water-filled nanotube model for amyloid fibrils formed as polymers of the Asp2Glni5Lys2 peptide. This model has been called //-helical (Kishimoto et al., 2004 Merlino et al., 2006), but it differs from known //-helices in that (i) it has circular coils formed by uniform deformation of the peptide //-conformation with no turns or linear //-strands, as are usually observed in //-solenoids and (ii) it envisages a tubular structure with a water-filled axial lumen instead of the water-excluding core with tightly packed side chains that is characteristic of //-solenoids. [Pg.60]

Figure 20.6 illustrates the test procedure. The key model inputs are defined at the left of the illustration and the outputs to the right. Only the essential input variables are shown here others are in fact used by the model but they are either constant for all plant operating conditions or the model equations are not particularly sensitive to them. [Pg.265]

A plot is made of the value of log(aT) for each temperature against the corresponding temperature value as shown in Figure 8.5 (sometimes absolute temperature is used, although mathematically this is unnecessary since temperature differences are in fact used for the shift). The shift factor should obey the WFF equation ... [Pg.105]


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