F-type doubling

This behaviour is very similar to that in a 77 — A vibrational transition in a linear polyatomic molecule (Section 6.2.4.1) in which the splitting is known as f-type doubling. Quantitatively, though, H-type doubling is often a much larger effect. 

Unresolved hyperfmc component. ) Unresolved /f-type doubling. 

Keywords Rotational constants, centrifugal distortion constants, rotation-vibration interaction constants, f-type doubling constants, anharmonic and Coriolis coupling constants... 

Details of the extended triple zeta basis set used can be found in previous papers [7,8]. It contains 86 cartesian Gaussian functions with several d- and f-type polarisation functions and s,p diffuse functions. All cartesian components of the d- and f-type polarization functions were used. Cl wave functions were obtained with the MELDF suite of programs [9]. Second order perturbation theory was employed to select the most energetically double excitations, since these are typically too numerous to otherwise handle. All single excitations, which are known to be important for describing certain one-electron properties, were automatically included. Excitations were permitted among all electrons and the full range of virtuals. 

In re Lonardo, 119 F.3d 960, 965 (Fed. Cir. 1997) See In re Goodman, 11 F.3d 1046, 1052 (Fed. Cir. 1993). The Patent Office allows a terminal disclaimer to cure an obviousness-type double patenting rejection only when the same entity owns both patents. 

Given the high regioselectivity, the type of addition in the insertion step must always be the same. It was found that in the polymerization of cis- and trans-[l-2H ]-propene a yyn-type double-bond opening takes place during insertion, eventually resulting in em/iro-diisotactic and f/ireo-diisotactic polymers, respectively 332-334... 

The structures and biosynthetic pathways of several of the prostaglandins are indicated in Fig. 21-7. Prostaglandins are usually abbreviated PG with an additional letter and numerical subscript added to indicate the type. The E type are (3-hydroxyketones, the F type 1,3-diols, and the A type a, (3-unsatur-ated ketones. Series 2 prostaglandins arise from arachidonic acid, while series 1 and 3 arise from fatty acids containing one fewer or one more double bond, respectively (Fig. 21-7). Additional forms are known.257 259... 

The type of the B-B-bond is double-three-center, the type of the B-pH-bonds is three-center, and the type of the B-H,-bonds is single. There are two DE-systems of three-center bonds, the B-B bond is described by two frmd-structures with type double-three-center, each belonging to one of the f/jree-cen/er-DE-systems. The atom-descriptors for the p-Hs contain the following entries concerning the electron distribution ... 

The site-selective addition of nitrosyl chloride to an f-configurated double bond, determined by kinetic studies18 with acyclic and cyclic (E)- and (Z)-alkenes in chloroform or by the reactions with (Z,E, )-1,5,9-cyclododecatriene19 and (Z,E)-, 5-cyclodecadiene"fl in dichloromethane, can be explained in terms of conformational stability in the four-centered transition state or by a syn-type addition however, the configuration of the products of such reactions was not elucidated. 

TABLE 1. Double set of f-type functions for metal (M ) ions"... 

Double set of single gaussian f-type functions (seven components) with exponents f and fz. 

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