F Hydrogen disulfide

Hydrogen cyanide /V-oxide, see Fulminic acid, 0380 f Hydrogen disulfide, 4478 Hydrogen fluoride, 4288 f Hydrogen (Gas), 4447... 

Gagnaire F, Simon P, Bonnet P, et al. 1986. The influence of simultaneous exposure to carbon disulfide and hydrogen sulfide on the peripheral nerve toxicity and metabolism of carbon disulfide in rats. Toxicol Lett 34 175-183. 

Treatment of 2-methylthiirane with f-butyl hydroperoxide at 150 °C in a sealed vessel gave very low yields of allyl disulfide, 2-propenethiol and thioacetone. The ally derivatives may be derived from abstraction of a hydrogen atom from the methyl group followed by ring opening to the allylthio radical. Percarbonate derivatives of 2-hydroxymethylthiirane decompose via a free radical pathway to tar. Acrylate esters of 2-hydroxymethylthiirane undergo free radical polymerization through the double bond. 

Recently it has been shown that anhydrous hydrogen fluoride exerts a selective solvent action on sulfur compounds and can be used satisfactorily for the desulfurization of kerosenes. In some respects it behaves similarly to sulfuric acid. Points of difference, however, are that it does not oxidize mercaptans to disulfides and that it can be used over a wide temperature range, 30° to 150° F., without affecting results. Hydrogen fluoride does not yet seem to have been used in full scale commercial units. 

Watts, S.F. (2000) The mass budgets of carbonyl sulfide, dimethyl sulfide, carbon disulfide and hydrogen sulfide. Atmos. Environ. 34, 761-779. 

A tank ship loaded a cargo of liquid sulfur (temperature 260°- 280°F) (127°- 138°C) on to a heel of crude oil. The reaction between liquid sulfur and petroleum generates toxic gases, including hydrogen sulfide, carbon disulfide and sulfur dioxide. The ship s crew was hospitalized and the ship, seeking a port of refuge, was denied entrance to several harbors until the reaction had run to completion as the sulfur cooled and eventually solidified. 

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