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Extraction Solvent, Solubility Parameter

Shown in Figure 6 is a plot of the viscosity of samples 3 and 5 plotted as a function of temperature. The viscosities were measured using an Instron Capillary Rheometer at a shear rate of 450 sec, The extracted solvent solubility parameters for samples 3 and 5 were 8.46 and 8.79 respectively. Figure 6 shows that the... [Pg.251]

Shown in Figure 7 is a plot of the glass transition temperature of the different fractions plotted as a function of the extraction solvent solubility parameter. [Pg.251]

VARIATION IN GLASS TRANSITION TEMPERATURE FOR EXTRACTED CAT CRACKER BOTTOM PITCH FRACTIONS AS A FUNCTION OF THE EXTRACTION SOLVENT SOLUBILITY PARAMETER... [Pg.255]

All PVC plasticisers have a solubility parameter similar to that of PVC. It appears that differences between liquids in their plasticising behaviour is due to differences in the degree of interaction between polymer and plasticiser. Thus such phosphates as tritolyl phosphate, which have a high degree of interaction, gel rapidly with polymer, are more difficult to extract with solvents and give compounds with the highest brittle point. Liquids such as dioctyl adipate, with the lowest interaction with polymer, have the converse effect whilst the phthalates, which are intermediate in their degree of interaction, are the best allround materials. [Pg.330]

Solubility parameters can be a useful guide to solvent selection, but precise quantitative relationships between solvent properties and extraction rates are not yet possible [37]. As an illustrative example we mention extraction of Irganox 1010 from PP [37]. Freeze-ground PP was extracted at 120 °C with 2-propanol,... [Pg.59]

Vandenburg et al. [37,489] have described the use of Hildebrand solubility parameters in a simple and fast solvent selection procedure for PFE of a variety of polymers. Hildebrand parameters for several common solvents and polymers are presented in Tables 3.2 and 3.34, respectively. When the proper solvent mixture for the polymer was determined, PFE resulted in essentially the same recoveries as the traditional extraction methods, but used much less time and solvent. PFE can be used to give very fast extractions and appears to offer the greatest flexibility of solvents and solvent mixtures. The method is ideal for a laboratory which analyses a large number of different polymers. [Pg.119]

The use of the Hildebrand solubility parameter approach to aid solvent selection with a few simple experiments, starting from the liquid solvents used in traditional extraction methods, limits the efforts needed in method development. As for other extraction... [Pg.120]

In reality, finding a suitable solvent is not as easy as simply matching the polymer s solubility parameter (8 value). It is also important to take into account the effects of polymer crystallinity (as in the case of aPP and iPP, LDPE and HDPE). Because of their various chemical structures, it may be necessary to experiment with solvent, temperature, and time conditions to optimise the extraction strategy. [Pg.148]

FIGURE 3 2 Solvent extraction efficiencies (EF) as functions of dielectric constants (D), solubility parameters (6), and polarity parameters (P and E -). Solvents studied silicon tetrachloride, carbon disulfide, n pentane. Freon 113, cyclopentane, n-hexane, carbon tetradiloride, diethylether, cyclohexane, isooctane, benzene (reference, EF 100), toluene, trichloroethylene, diethylamine, chloroform, triethylamine, methylene, chloride, tetra-hydrofuran, l,4 dioxane, pyridine, 2 propanol, acetone, ethanol, methanol, dimethyl sulfoxide, and water. Reprinted with permission from Grosjean. ... [Pg.47]

If Z9b(ai) can be equated with P calculated from the entries in Table 2.5, then Z9b(a2) in any other solvent Ab can be estimated from Eq. (2.62). Equation (2.62) is actually a combination of four expressions of the form of Eq. (2.8) (see section 2.2.2), two for water and solvent Ai and two for water and solvent A2, presuming them to be immiscible pairs of liquids. It employs concentrations on the mole fraction scale, and assumes that the systems behave as regular solutions (which they hardly do). This eliminates the use of the solubility parameter 8 of water, which is a troublesome quantity (see Table 2.1). Solvent Ai need not, of course, be 1-octanol for Eq. (2.62) to be employed, and it suggests the general trends encountered if different solvents are used in solvent extraction. [Pg.83]

Table V lists the common solvents used for cleaning XAD resins and their respective solubility parameters. Methanol and acetonitrile [which are used in the cleanup procedure of Junk et. al. (5)] have very different total solubility parameters than the compounds listed in Table IV. Thus, they should be less efficient for eluting the resin contaminants from the resin polymers. This situation explains the GC profile results, which show large numbers and high concentrations of contaminants after the successive 24-h Soxhlet extractions using methanol, acetonitrile, and ethyl ether (Figure 2). Table V lists the common solvents used for cleaning XAD resins and their respective solubility parameters. Methanol and acetonitrile [which are used in the cleanup procedure of Junk et. al. (5)] have very different total solubility parameters than the compounds listed in Table IV. Thus, they should be less efficient for eluting the resin contaminants from the resin polymers. This situation explains the GC profile results, which show large numbers and high concentrations of contaminants after the successive 24-h Soxhlet extractions using methanol, acetonitrile, and ethyl ether (Figure 2).
The cut line for extraction with polar solvents such as phenol, cresol, n-methylpyrrollidone, and furfural is slanted in the opposite direction from solvent precipitation, because the solubility parameter of the polar solvent lies to the right of the composition map. Thus, the cut line is the left-hand wing of the solubility bell curve of the polar solvent. It moves up and down and left and right as the solubility parameter of the polar solvent is changed. Furthermore, it is also sensitive to the operating conditions of the extraction, such as temperature and solvent-to-oil ratio. [Pg.134]

Solubility Parameters of the Most Common Fluids for Supercritical Fluid Extraction and Chromatography Solubility Parameters of Supercritical Fluids Solubility Parameters of Liquid Solvents Instability of Modifiers Used with Supercritical Fluids... [Pg.217]

The following table provides the solubility parameters, 8, for the most common fluids and modifiers used in supercritical fluid extraction and chromatography. The data presented in the first table are for carrier or solvent supercritical fluids at a reduced temperature, T of 1.02 and a reduced pressure, P of 2. These values were calculated with the equation of Lee and Kesler.1 2 The data presented in the second table are for liquid solvents that are potential modifiers.3... [Pg.265]

In this table, we provide solubility parameters for some liquid solvents that can be used as modifiers in supercritical fluid extraction and chromatography. The solubility parameters (in MPa1/2) were obtained from reference 3, and those in cal1/2cm 3/2 were obtained by application of Equation 4.1 for consistency. It should be noted that other tabulations exist in which these values are slightly different, since they were calculated from different measured data or models. Therefore, the reader is cautioned that these numbers are for trend analysis and separation design only. For other applications of cohesive parameter calculations, it may be more advisable to consult a specific compilation. This table should be used along with the table on modifier decomposition, since many of these liquids show chemical instability, especially in contact with active surfaces. [Pg.266]


See other pages where Extraction Solvent, Solubility Parameter is mentioned: [Pg.251]    [Pg.251]    [Pg.251]    [Pg.254]    [Pg.76]    [Pg.755]    [Pg.56]    [Pg.59]    [Pg.81]    [Pg.91]    [Pg.91]    [Pg.99]    [Pg.113]    [Pg.116]    [Pg.119]    [Pg.121]    [Pg.135]    [Pg.52]    [Pg.379]    [Pg.41]    [Pg.156]    [Pg.79]    [Pg.412]    [Pg.15]    [Pg.398]    [Pg.327]    [Pg.227]    [Pg.515]    [Pg.83]    [Pg.1980]    [Pg.412]    [Pg.438]   
See also in sourсe #XX -- [ Pg.328 ]




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Extracting parameters

Extraction parameters

Extractives solubility

Solubility paramete

Solubility parameter

Solubility solvents

Solvent parameter

Solvents solubility parameter

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