Explosive behavior

See, Ree F and Vanthiel M 1986 Modeling explosive behavior Energy Techno . Rev. UCRL-52000-86-3, 41... 

D. Price and A. R. Clairmont, Jr., "Explosive Behavior of Nitroguanidine," in Proceedings of the 12th Symposium on Combustion, Combustion Institute, Pittsburgh, Pa., 1969, p. 761. 

J. H. McLain, Principles of Explosive Behavior, Engineering Design Handbook, AMC 706-180, AMC, Alexandria, Va., 1972. 

EngrgDesHndbk, Principles of Explosive Behavior , AMCP 706-180 (Apr 1972), AD 900 260 148) J. Hansson, Ed, Third Symposium... 

An impressive example of the impact of miniaturization on the explosion limit has been given for the oxyhydrogen reaction [18]. For a conventional reactor of 1 m diameter, explosive behavior sets in at 420 °C at ambient pressure (10 Pa). An explosion occurs at about 750 °C, when the reactor diameter is decreased to about 1 mm. A further reduction to 100 pm shifts the explosive regime further to higher pressures and temperatures. 

Explosion behavior depends on a large number of parameters. A summary of the more important parameters is shown in Table 6-6. 

Explosion behavior is difficult to characterize. Many approaches to the problem have been undertaken, including theoretical, semiempirical, and empirical studies. Despite these efforts, explosion behavior is still not completely understood. Practicing engineers, therefore, should use extrapolated results cautiously and provide a suitable margin of safety in all designs. 

The maximum rate of pressure increase indicates the robustness of an explosion. Thus the explosive behavior of different materials can be compared on a relative basis. The maximum rate is also used to design a vent for relieving a vessel during an explosion before the pressure ruptures the vessel or to establish the time interval for adding an explosion suppressant (water, carbon dioxide, or Halon) to stop the combustion process. 

The subscript in vessel is for the reactor or building. The subscript experimental applies to data determined in the laboratory using either the vapor or dust explosion apparatus. Equation 6-20 allows the experimental results from the dust and vapor explosion apparatus to be applied to determining the explosive behavior of materials in buildings and process vessels. This is discussed in more detail in chapter 9. The constants KG and KSt are not physical properties of the material because they are dependent on (1) the composition of the mixture, (2) the mixing within the vessel, (3) the shape of the reaction vessel, and (4) the energy of the ignition source. It is therefore necessary to run the experiments as close as possible to the actual conditions under consideration. 

Blowout panels are designed to provide the proper relief area, depending on a number of design factors. These include the explosive behavior of the dust or vapor, the maximum overpressure allowable in the structure, and the volume of the structure. Design standards are available.15... 

Engineering Design Handbook, Principles of Explosive Behavior, AMCP 706-180, Headquarters, U.S. Army Materiel Command, Washington, D.C., 1972. 

See also Acetoacetyl-CoA in citric acid cycle, 6 633 Acetyl cyclohexanesulfonyl peroxide (ACSP), 74 282 78 478 Acetylene(s), 7 177-227, 227-228 25 633 addition of hydrogen chloride to, 73 821 from calcium carbide, 4 532, 548 carbometalation of, 25 117 as catalyst poison, 5 257t chemicals derived from, 7 227-265 decomposition of, 70 614 Diels-Alder adduct from cyclopentadiene, 8 222t direct polymerization, 7 514 economic aspects of, 7 216-217 explosive behavior of, 7 181-187 as fuel, 7 221-222 health and safety factors related to, 7 219... 

Explosive behavior, acetylene, 1 181-186 Explosive compounds, properties of,... 

TNC.66.1. Prigogine, G. Nicolis, M. Mansour, and F. Baras, Fluctuations and explosive behavior in nonlinear chemical systems, in Proceedings, Sympo mmNonlinear Problems in Energy Engineering, Argonne National Laboratory, 1983. 

Children with chronic manic symptoms (i.e., lacking episodes) are most accurately diagnosed as bipolar NOS (Nottelman et ah, 2001). The chief symptoms in children with manic symptoms/bipolar NOS appear to be mood lability and explosive behavior. The explosive... 

Clairmont, Jr, "Explosive Behavior of Nitro-guanidine , Ibid, pp 761-70 23d) L.G. 

Price, "Contrasting Patterns in the Behavior of High Explosives , llthSympCombstn (1967), p 695, Fig 4, which shows that for Group 2 explosives deton vel at first increases with density, then it falls, and finally the detonation fails) 10) D. Price et al, "Explosive Behavior of Ammonium Perchlorate , Combustion Flame 11, p 419, Figs 5 6 (1967) (Detonation velocity vs density of AP curves show that increase of density above critical values results in failures)... 

D. Price et al, "Explosive Behavior of Ammonium Perchlorate , Combustion 8t Flame 11, 415-25 (Oct 1967) 16) C.G. Dunkle, private... 

Anon, Principles of Explosive Behavior AMCP 706-180 (1972) 20) R.E. Winter, Expl Div Newsletter PA July 1973... 

S.J. Jacobs et al, Ibid, pp 413--26 21) O.E. Jones, Proc 12th Annual Symp on Behavior Utilization of Explosive in Engineering Design (March 1972), pp 130-138 22) J.P. Sumner, Ibid, pp 225-34 23) Anon AMCP 706-180 Principles of Explosive Behavior (April 1972)... 

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