Homogeneous exchange

The electrochemical method allows, by means of electron transfer at a given electrode, the formation of a species (named also electron carrier) able to exchange homogeneously electron(s) with a less electroactive organic derivative (Scheme 1). Tlie homogeneous redox process is assumed to occur in high yield, and then the indirect electron exchange can happen either in solution or very close to the interface. 

Membrane ion exchange, homogeneous or microporous polymer with positively or negatively charged fixed ions... 

A homogenizer or rotary positive pump may be used as a timing or metering pump to provide a positive, fixed flow through the pasteurization system (Fig. 6). The pump is placed ahead of the heater and the holding section. Various control drives assure that the pasteurized side of the heat exchanger is at a higher (7 kPa (1 psi)) pressure than the opposite side. 

Macromixing is estabflshed by the mean convective flow pattern. The flow is divided into different circulation loops or zones created by the mean flow field. The material is exchanged between zones, increasing homogeneity. Micromixing, on the other hand, occurs by turbulent diffusion. Each circulation zone is further divided into a series of back-mixed or plug flow cells between which complete intermingling of molecules takes place. 

Homogeneous reactions. Homogeneous noncatalytic reactions are normally carried out in a fluidized bed to achieve mixing of the gases and temperature control. The sohds of the bed act as a heat sink or source and facihtate heat transfer from or to the gas or from or to heat-exchange surfaces. Reaclious of this type include chlorination of hydrocarbons or oxidation of gaseous fuels. 

Base catalysis is most effective with alkali metals dispersed on solid supports or, in the homogeneous form, as aldoxides, amides, and so on. Small amounts of promoters form organoalkali comnpounds that really contribute the catalytic power. Basic ion exchange resins also are usebil. Base-catalyzed processes include isomerization and oligomerization of olefins, reactions of olefins with aromatics, and hydrogenation of polynuclear aromatics. 

Condensations of aldehydes and ketones are catalyzed homogeneously by acids and bases, but solid bases are preferred, such as anion exchange resins and alkah or alkaline earth hydroxides or phosphates. 

On the second startup no ignition in the bottom occurred, but it was observed here also that a significant drop in oxygen concentration occurred between the reactor bottom and the heat exchanger, without loss of acrolein concentration. The homogeneous reaction also produced acrolein, just in much lower selectivity. Then, on the third day of... 

Bead Size - The resins must be in the form of spherical granules of maximum homogeneity and dimensions so that they do not pack too much, the void volume among their interstices is constant for a given type, and the liquid head loss in percolation remains acceptable. Most ion-exchange resins occur as small beads or granules usually between 16 and 50 mesh in size. 

For an adsorbate which is homogeneous within the patches of reconstructed and unreconstructed surface only the diffusional exchange of mass between these two types contributes to the time evolution. The equations of motion read... 

However, it should be mentioned that the dissolution process of a solid, crystalline complex in an (often relatively viscous) ionic liquid can sometimes be slow. This is due to restricted mass transfer and can be speeded up either by increasing the exchange surface (ultrasonic bath) or by reducing the ionic liquid s viscosity. The latter is easily achieved by addition of small amounts of a volatile organic solvent that dissolves both the catalyst complex and the ionic liquid. As soon as the solution is homogeneous, the volatile solvent is then removed in vacuo. 

The slower rate of hydrolysis of alkyl substituted esters in the presence of the cation exchange resin can be explained by the assumption that the alkyl groups interfere more in the formation of the intermediate complex on the resin surface than in the homogeneous system. The efficiency of the resin q was less than unity... 

The basic mix is made up in liquid form, pasteurized, homogenized and cooled, using chilled water in plate heat exchangers. It is then aged for a few hours and, for this, it will be stored at 2-3°C in jacketed tanks, with chilled water in the jacket. 

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