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Evaluation of microporosity

If the isotherm is of Type I with a sharp knee and a plateau which is horizontal (cf. Fig. 4.10) the uptake n, at a point close to saturation, say p/p = 0-95, is then a measure of the micropore volume when converted to a liquid volume (by use of the density of the liquid adsorptive), it may be taken as actually equal to the micropore volume. [Pg.209]

More often, however, microporosity is associated with an appreciable external surface, or with mesoporosity, or with both. The effect of microporosity on the isotherm will be seen from Fig. 4.11(a) and Fig. 4.12(a). In Fig. 4.11(a) curve (i) refers to a powder made up of nonporous particles and curve (ii) to a solid which is wholly microporous. However, if the particles of the powder are microporous (the total micropore volume being given by the plateau of curve (ii)), the isotherm will assume the form of curve (iii), obtained by summing curves (i) and (ii). Like isotherm (i), the composite isotherm is of Type II, but because of the contribution from the Type 1 isotherm, it has a steep initial portion the relative enhancement of adsorption in the low-pressure region will be reflected in a significantly increased value of the BET c-constant and a shortened linear branch of the BET plot. [Pg.210]

whilst a powder composed of nonporous particles gives rise to an isotherm of Type II, the converse is not necessarily true if a solid yields a Type II isotherm, it is not necessarily free of micropores. Similarly, though a Type IV isotherm signifies the presence of mesoporosity, it does not prove the absence of microporosity. -  [Pg.211]

A high value of the BET constant c is a useful preliminary indication of the presence of microporosity, but it does not enable one to estimate the micropore volume itself, that is in effect to break down the composite isotherm (iii) into its components (i) and (ii). [Pg.211]

A number of methods which have been proposed for the evaluation of microporosity from Type II and Type IV isotherms will now be described. [Pg.211]


It follows that the applicability of the nonane pre-adsorption method for the evaluation of microporosity is restricted to adsorptives such as nitrogen which are used at temperatures far below ambient and which have negligible solubility in soUd or liquid nonane. [Pg.242]

The equilibration time for the adsorption in some microporous materials, like CMS and carbonized chars, may be extremely long that may be a source of error for the evaluation of microporosity. For example, this occurs for N2 at 77 K in samples with narrow microporosity (size below 0.7 nm), where the size of the adsorbate molecule is similar to the size of the pore entrance. In this case, contrary to the exothermic nature of the adsorption process, an increase in the temperature of adsorption leads to an increase in the amount adsorbed. In this so-called activated diffusion process, the molecules will have insufficient kinetic energy, and the number of molecules entering the pores during the adsorption equilibrium time will increase with temperature [9,23],... [Pg.124]

However, the characterization of composite isotherms, i.e those indicating the presence of supermicropores and/or mesopores, requires the combined application of more than one method to deduce the PSD extending over the micro- and mesopore range e g. the Barrett-Joyner-Halenda (BJH) method [6] to evaluate the mesopore range and one of the DR-DA-DS, HK, BP (i.e. the method of Mikhail et al. [7]) for the evaluation of microporosity. Micropore volume and surface area estimates are practically obtained by using the empirical a,5-plot method [1]. [Pg.27]

S.J. Gregg and J.F. Langford, Evaluation of microporosity with special reference to a carbon black. Trans. Faraday Soc., 65 (1969) 1394. [Pg.113]

EVALUATION OF MICROPOROSITY IN ACTIVATED CARBONS WITH HIGH ASH (CrjOj) CONTENT... [Pg.449]

Jaroniec, M., Gilpin, R. K., Kaneko, K. and Choma, J., Evaluation of energetic heterogeneity and microporosity of activated carbon fibers on the basis of gas adsorption isotherms, Langmuir, 1991, 7(1 1), 2719 2722. [Pg.113]

The equlibrium between the bulk fluid and fluid adsorbed in disordered porous media must be discussed at fixed chemical potential. Evaluation of the chemical potential for adsorbed fluid is a key issue for the adsorption isotherms, in studying the phase diagram of adsorbed fluid, and for performing comparisons of the structure of a fluid in media of different microporosity. At present, one of the popular tools to obtain the chemical potentials is an approach proposed by Ford and Glandt [23]. From the detailed analysis of the cluster expansions, these authors have concluded that the derivative of the excess chemical potential with respect to the fluid density equals the connected part of the fluid-fluid direct correlation function (dcf). Then, it follows that the chemical potential of a fluid adsorbed in a disordered matrix, p ), is... [Pg.304]

For a more detailed evaluation of the microporosity, one must be able to interpret the energy of immersion data. At present, there are two procedures favoured by different investigators. [Pg.227]

Various procedures have been proposed for the evaluation of the true intracrystalline capacity and the external surface area (see Sayari et al., 1991). The as-method is one way of analysing composite isotherms, which has been applied to nitrogen isotherms on different samples of ZSM-5 (Sing, 1989). This approach was used by Gil et al. (1995) in their recent study of the microporosity of pillared clays and zeolites. By this means, mesopores were estimated to have contributed about 25% to the total pore volume of a commercial sample of HZSM-5. [Pg.390]

Worthington, P.F., Pallat, N., and Toussaint-Jackson, J.E., 1989. Influence of microporosity on the evaluation of Hydrocarbon saturation, SPEFE (June 1989), 203 Trans, AIME, 287. [Pg.490]

In this study, we have prepared and characterized montmorillonite pillared with Al and La in different proportions. The structural and textural parameters of the materials were compared with those of montmorillonite pillared only with Al. We have applied classical and new models to low pressure nitrogen adsorption data to obtain a quantitative evaluation of the microporosity of the synthesized materials and their evolution under thermal treatments. [Pg.617]

The assumption of the EO chains being intimately mixed with the condensing silica has crucial consequences regarding the porosity of the solidified material after removal of the template, as each EO chain will create its own cavity or molecular imprint in the amorphous silica wall. The EO chains can therefore be expected to act as a porogen that creates microporosity within the walls of the mesoporous structure. This has indeed been evidenced experimentally. The combination of a complete evaluation of the small-angle X-ray diffraction data, in combination with nitrogen sorption experiments prove that mesoporous sil-... [Pg.44]

Comment. Gas sorption analysis is a well-established tool for the characterization of open porous solids. For aerogels the method provides reliable information on the surface area. However, care has to be taken in case of microporous aerogels here a well-equilibrated isotherm in combinatiOTi with the right choice of the evaluation range will still yield reliable values for the microporosity and the specific surface area. For detailed analysis of microporosity measurements with CO2 at 273 K are recommended. [Pg.482]

While a number of established characterization methods exist for mesopores and macropores, the assessment of microporosity is much less advanced, due to experimental difficulties and the lack of a suitable model for the interpretation of the isotherm data. Obtaining accurate experimental isotherms is hampered by the long equilibration times required at the low liquid nitrogen temperatures. In order to overcome this limitation the micropore structure evaluation can be based on isotherms of carbon dioxide or other vapors obtained at higher temperatures, provided that a suitable equilibrium model for the sorption of non spherical molecules is available. [Pg.688]

Based on such results of microporosity. X-ray diffraction and small angle scattering evaluation as well as on density measurements, and finally stimulated by ROLAND s carbon fibre model (26) a 2-dimensional model for glasslike carbon was derived by us as shown in fig. 8, left hand side (18). Simultaneously, by other research groups, the first transmission electron microscopic pictures of glass like carbons (19) confirmed this assumed structure (fig.8, right hand side). [Pg.111]

Rodriguez-Reinoso F, Martin-Martinez JM, Molina Sabio M, Torregrosa R, Garrido-Segovia I. Evaluation of the microporosity in activated carbons by n-nonane pre-adsorption. J Coll InterfSci... [Pg.241]

In order to throw some light on these contradictory results and on the choice of the method to evaluate the microporosity of activated carbons, the CO2 adsorption isotherms were fitted to the DR equation. Only in the case of PC 12 the experimental data showed a linear fit to the DR equation over the entire range of relative pressures. The exponent of PC12 was n=1.95, close to the ideal value (n=2) of the DR equation. In the rest of the series, there are two linear ranges, at either low or high relative pressures. [Pg.324]

The main objetive of the work described here is to evaluate the microporosity in a series of activated carbons with increa.sing burn-off and ash (CrjOj) content using the isotherms on non-porous carbon and Cr Oj. samples as references in the< -plot method and the comparison with results obtained from the Dubinin theory and n-nonane preadsorption. [Pg.449]

Perhaps the most direct method of evaluating microporosity is to fill up the micropores with some suitable adsorbate whilst leaving the mesopores, macropores and external surface free. The use of n-nonane as a preadsorbate was proposed by Gregg and Langford on the basis of earlier work on the adsorption of n-alkanes C, to C, on ammonium phos-phomolybdate, a microporous solid. This work had shown that the rate at... [Pg.211]


See other pages where Evaluation of microporosity is mentioned: [Pg.209]    [Pg.119]    [Pg.226]    [Pg.184]    [Pg.32]    [Pg.438]    [Pg.209]    [Pg.119]    [Pg.226]    [Pg.184]    [Pg.32]    [Pg.438]    [Pg.860]    [Pg.532]    [Pg.27]    [Pg.33]    [Pg.194]    [Pg.183]    [Pg.238]    [Pg.436]    [Pg.475]    [Pg.181]    [Pg.216]    [Pg.413]    [Pg.377]    [Pg.409]    [Pg.101]    [Pg.414]    [Pg.641]   


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Microporosity

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