2- Ethyl-5-methylcyclohexanol

METHYLCYCLOHEXANOL cis-2-HETHYLCYCLOHEXANOL trans-2-METHYLCYCLOHEXANOL cis-3-METHYLCYCLOHEXANOL trans-3-METHYLCYCLOHEXANOL cis-4-METHYLCYCLOHEXANOL trans-4-METHYLCYCLOHEXANOL 5-METHYL-2-HEXANONE n-BUTYL PROPIONATE ETHYL ISOVALERATE ISOPENTYL ACETATE n-PENTYL ACETATE n-PROPYL n-BUTYRATE n-HEPTANOIC ACID ETHYL-3-ETHOXYPROPIONATE... 

Mercapto-l-methyl ethyl)-5-methylcyclohexanol Cyclohexanol-2-(1-mercapto-l-methylethy)-5-methyl-, [1R-(la,2a,5a)]- ... 

C9H180 1 -ethyl-O-methylcyclohexanol 62067-44-1 456.62 39.732 2 18096 C9H1803 acetic acid 3-heptanol ester 39920-56-4 442.99 38.434 2... 

The reaction of bicyclo[4.1.0]heptane with diborane and subsequent treatment with hydrogen peroxide produced predominantly cyclohexylmethanol (5b) in high yield.Under modified experimental conditions small amounts of isomeric methylcyclohexanol (6b) and cycloheptanol (7b) were isolated. In contrast to the hydroboration of alkenes, the cyclopropane cleavage reaction is inhibited by ethereal solvents such as diethyl ether, tetrahydrofuran or 2-methoxy-ethyl ether. Bicyclo[3.1.0]hexane reacted with diborane in a similar fashion to give mainly cyclopentylmethanol (5a).The reaction of l-methylbicyclo[4.1.0]heptane gave a mixture of cis- and tram-(2-methylcyclohexyl)methanol (5c) in an initial ratio of 60 40. Spiro[2.5]octane reacted with diborane to yield only products derived from scission at the spiro carbon. The main product was 2-cyclohexylethanol (8). ... 

M ethy Icy clo hexano 1 ds-2-Methylcyclohexanol trans-2-Methylcyclohexanol Methylcyclopentane 1 - M ethy Icy clo p ent ene 3-Methylcyclopentene Methyldichlorosilane Methylethyl ether Methylethyl ketone Methylethyl sulfide Methyl formate Methylisobutyl ether Methylisobutyl ketone Methyl Isocyanate Methylisopropyl ether Methylisopropyl ketone Methylisopropyl sulfide Methyl mercaptan Methyl methacrylate 2-Methyloctanoic acid 2- M ethy lp ent ane Methyl pentyl ether 2- M ethy lp ro p ane 2- M ethyl- 2- p rop ano 1 2-Methyl propene Methyl propionate Methylpropyl ether Methylpropyl sulfide Methylsilane... 

Dialkylaminopyridine (DAAP) catalysts are effective catalysts for acylation reactions. The acetylation of 1- methylcyclohexanol by acetic anhydride in the presence of triethylamine (TEA) was used as a test reaction for the polymer-bond DAAP. The conversion of the starting alcohol was measured by GC analysis using ethyl benzene as an internal standard. The initial rates were studied and a first order analyses showed that the rate constant for reaction (1) was 0.178 h for 4-dimethylaminopyridine (DMAP), and 0.120 h for PNIPAM-DAAP-MR. 

Mercaptopropionic acid Methylcyclohexanol Methyl ethyl ketoxime N-Nitrosodiethylamine N-Nitrosodimethylamine Nitrosophenylhydroxylamine ammonium salt Oat (Avena sativa) extract Octadecyl 3-mercaptopropionate Octylphenol 4,4(5H)-Oxazoledlmethanol, 2-(heptadecenyl)-Pansy (Viola tricolor) extract Phenyl neopentylene glycol phosphite Sodium citrate Sulfur dioxide a-Terpineol 2,2, 4,4 -Tetrahydroxy, 5,5 -di-t-butylbenzophenone Tetraisopropyl di (dioctylphosphito) titanate Thymol Toluhydroguinone 2,2,4-Trimethyl-1,2-dihydroquinoline Trimethyl quinoline 2,4,6-Tris (dimethylaminomethyl) phenol Ubiquinone Wheat (Triticum vulgare) germ oil Zeaxanthin Zinc dialkyl dithlophosphate antioxidant mfg. 

Methoxypropyl formamide Methylamine N-Methylaniline Methyl behenate o-Methylbenzyl alcohol 2-Methyl-1-butanol Methyl caproate Methylcyclohexanol acetate N-Methylcyclohexylamine N-Methylethanolamine Methylhydrazine Methyl-(S)-lactate 3-Methylpentane Methyl phthalyl ethyl glycolate 1-Methylpiperidine 2-Methylpropanal Mixed terpenes Naphtha, heavy aliphatic Naphtha, heavy alkylate Naphtha, heavy aromatic Naphtha, hydrodesulfurized heavy Naphtha, hydrotreated heavy Naphtha, hydrotreated light Naphthalene Naphtha, light aliphatic Naphtha, light alkylate Naphtha, solvent-refined light Naphthenic acid Naphthol spirits Neoheptane... 

Methylcyclohexanol Methylcyclohexanone Methyl ethyl ketone Methyl isobutyl ketone Methyl lactate... 

Methylcyclohexanol 2-Nitropropane PPG-2 methyl ether PPG-3 methyl ether Propylene glycol methyl ether acetate Propylene glycol phenyl ether Tetradecene-1 1,1,1-Trichloroethane Tripropylene glycol ethyl ether solvent, oils/fats Decahydronaphthalene solvent, oils/greases removal Perfluoroheptane Perfluorohexane Perfluoropentane solvent, ointments... 

Erucamide 2-Ethyl-1-butanol Ethyl chloride Ethylene chlorohydrin Ethyl ether 2-Ethylhexyl acetate 2-Hexanone Isoamyl acetate Isocetyl salicylate Isopropyl ether dl-Limonene Methoxydiglycol Methoxyethanol acetate Methylcyclohexanol N-Methyl-2-pyrrolidone... 

Pentamethylene dibromide allowed to react with Mg in abs. tetrahydrofuran under argon, stirring continued 2 hrs. at room temp., ethyl acetate-[1- G] in tetrahydrofuran added dropwise, stirred 12 hrs. and allowed to stand 24 hrs. at ca. 20° 1-methylcyclohexanol-fl- G] (Y 77% purity 87%) refluxed 3 hrs. with pentachlorophenol j -methylcyclohexene-l- G (Y 90% containing ca. 18% startg. m.) passed repeatedly at 350° through a Pt-on-Al203 catalyst until Hg-elimination ceases -> toluene-[1- G] (Y 84-87% purity 97-99%). A. Rieker, K. Scheffler, and E. Muller, A. 670, 23 (1963). 

All operations were performed aecording to the standard Schlenk teehniques. Starting materials were of commercial origin, with the exception of S-2-bromoacetoxypropionic acid ethyl ester, the bromoacetate of D-menthol [(IS, 2R, 5S)-2-isopropyl-5-methylcyclohexanol] and L-menthol [(IR, 2S, 5R)-2-isopropyl-5-methylcyclo-hexanol] as well as of dicobalt octacarbonyl, which were prepared aeeording to published procedures. 

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