Ethyl-benzene isoamyl ether

Water with aniline, benzene, benzyl alcohol, carbon disulfide, carbon tetrachloride, chloroform, cyclohexane, cyclohexanol, cyclohexanone, diethyl ether, ethyl acetate, isoamyl alcohol, methyl ethyl ketone, nitromethane, tributyl phosphate or toluene. 

Temper- ature °C Methyl alcohol Ethyl alcohol Isoamyl alcohol Ethyl ether Acetone Benzene Toluene Carbon tetra- chloride... 

SYNS ANTHER BENZENE, (2-(3-METHYLBUTO-XY)ETHYL)- (2-(3-METHYLBUTOXY)ETHYL)-BENZENED PHENYLETHYL ISOAMYL ETHER... 

Crystallizes as six-sided prisms or plates from benzene, tnp220-22P. d 1.35. Almost insol in water and ether. Soluble in chloroform, acetic acid. One part dissolves in 455 pans ale or 80 parts boiling ale. Sparingly sol in most other organic solvents, May be crystallized from hot ale, benzene, petr ether, methyl ethyl ketone, isoamyl alcohol, acetophen -one, pyridine, or an alcohol-pyridiDe mixture. The salts tend to oil out, but can be crystallized by warming, redissolving, and slow cooling. 

Isoamyl acetate n-Amyl cyanide Benzene Benzyl ether 2 Bromoethyl acetate Chloroform Cinnamaldehyde Di-n amylarnine Di-n-butyl carbonate Diethvlacetic acid Diethylcnetnamme Diethyl formamide Diisobutyl ketone Diisopropvlamine Di-n-propvlamlme Ethyl alcohol Ethyl benzoate Ethyl ether Ethyl phenyUcetate Heptadecanol ... 

AI3-00040, see Cyclohexanol AI3-00041, see Cyclohexanone AI3-00045, see Diacetone alcohol AI3-00046, see Isophorone AI3-00050, see 1,4-Dichlorobenzene AI3-00052, see Trichloroethylene AI3-00053, see 1,2-Dichlorobenzene AI3-00054, see Acrylonitrile AI3-00072, see Hydroquinone AI3-00075, see p-Chloro-rrr-cresol AI3-00078, see 2,4-Dichlorophenol AI3-00085, see 1-Naphthylamine AI3-00100, see Nitroethane AI3-00105, see Anthracene AI3-00109, see 2-Nitropropane AI3-00111, see Nitromethane AI3-00118, see ferf-Butylbenzene AI3-00119, see Butylbenzene AI3-00121, see sec-Butylbenzene AI3-00124, see 4-Aminobiphenyl AI3-00128, see Acenaphthene AI3-00134, see Pentachlorophenol AI3-00137, see 2-Methylphenol AI3-00140, see Benzidine AI3-00142, see 2,4,6-Trichlorophenol AI3-00150, see 4-Methylphenol AI3-00154, see 4,6-Dinitro-o-cresol AI3-00262, see Dimethyl phthalate AI3-00278, see Naphthalene AI3-00283, see Di-rj-butyl phthalate AI3-00327, see Acetonitrile AI3-00329, see Diethyl phthalate AI3-00399, see Tributyl phosphate AI3-00404, see Ethyl acetate AI3-00405, see 1-Butanol AI3-00406, see Butyl acetate AI3-00407, see Ethyl formate AI3-00408, see Methyl formate AI3-00409, see Methanol AI3-00520, see Tri-ocresyl phosphate AI3-00576, see Isoamyl acetate AI3-00633, see Hexachloroethane AI3-00635, see 4-Nitrobiphenyl AI3-00698, see IV-Nitrosodiphenylamine AI3-00710, see p-Phenylenediamine AI3-00749, see Phenyl ether AI3-00790, see Phenanthrene AI3-00808, see Benzene AI3-00867, see Chrysene AI3-00987, see Thiram AI3-01021, see 4-Chlorophenyl phenyl ether AI3-01055, see 1.4-Dioxane AI3-01171, see Furfuryl alcohol AI3-01229, see 4-Methyl-2-pentanone AI3-01230, see 2-Heptanone AI3-01231, see Morpholine AI3-01236, see 2-Ethoxyethanol AI3-01238, see Acetone AI3-01239, see Nitrobenzene AI3-01240, see I idine AI3-01256, see Decahydronaphthalene AI3-01288, see ferf-Butyl alcohol AI3-01445, see Bis(2-chloroethoxy)methane AI3-01501, see 2,4-Toluene diisocyanate AI3-01506, see p,p -DDT AI3-01535, see 2,4-Dinitrophenol AI3-01537, see 2-Chloronaphthalene... 

Lead ethyl isoamyl dichloride is obtained in quantitative yield by chlorination of lead diethyl isoamyl chloride. It crystallises in. plates, sparingly soluble ixi water, insoluble in ether, ethyl acetate, or benzene. 

Lead n-propyl isoamyl dichloride is obtained from lead methyl n-propyl isoamyl chloride, and crystallises from hot alcohol, in which it is easily soluble, in plates, insoluble in benzene, ether, ethyl acetate, or water. The mlphide may be obtained in the usual way, and it is readily soluble in alcoliolic ammonium sulphide, sparingly in aqueous ammonium sulphide. 

Tasteless crystals from dil methanol, dec 171-173. Mg + 115.3 (c = 10 in chloroform). Potency 939 units/mg. Soly in water 9 units/ml (bioassay). Solubilities determined by Weiss et al. Antibiot. A Chemother. 7, 374 (1957) iu mg/ml at about 28 Water 0.075 methanol 7.3 ethanol 5.2 isopropanol 1.7 isoamyl alcohol 3.1 cyclohexane 0.115 benzene 0.60 toluene 0.39 peer etber 0.0 isooctane 0.055 carbon tetrachloride 0.50 ethyl acetate 1.65 isoamyl acetate 1.4 acetone 3.4 methyl ethyl ketone 3.65 ether 0.70. therap cat Antibacterial. 

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