Esters nitration

Hydroxyalkyl Alkylene Dinitramines and Their Nitrate Esters. Nitrate esters such as N,N -bis-(2-nitroxyethyl) ethylenedinitramine. [Pg.230]

Inorganic acid esters nitrates (e.g. methyl nitrate, nitroglycol, nitroglycerine), silicates (e.g. ethyl silicate), phosphates (e.g. triphenyl phosphate, tricresyl phosphate), mixed esters of nitric and hydrochloric acid (e.g. chlorohydrin dinitrate). [Pg.258]

Ethanolamine nitric ester nitrate (ethanolamine dinitrate) N03NH3CH2CH20N02 is a solid melting at 103°C. According to Naoum this compound can be prepared by nitrating ethanolamine [68], Aubry [69] has reported that a yield of 90-96% can be achieved in this reaction. This method of preparation has not been confirmed by some authors. Serious disadvantages of the substance include its inclination to absorb moisture, and the readiness with which it loses nitric acid owing to the wealdy basic properties of the amine [70],... [Pg.472]

Diethanolamine dinitric ester nitrate (diethanolamine trinitrate)... [Pg.472]

Triethanolamine trinitric ester nitrate (triethanolamine tetranitrate)... [Pg.473]

Merck (1976), 1241 (No 9347) Triethanolamine Tetranitrate. (Triethanolamine trinitric ester nitrate, Tris (j3-nitroxyethyl)-amine nitrate or Trinitroxy triethane amine nitrate). N(CH2. CH2.0N02)3. HN03 or [HN(CH2.CH2.0N02)3] N03, C6 Hj 3 N5 Oi 3 mw 347.24 N 20.17% OB to C02 —29.95% mp 74° (decompn), 62.7°, 62° (sep values). Hydrolyzed by w. Sol in hot ethanol insol in eth. Prepn is by nitration of triethanolamine nitrate with 97% nitric acid at —5°, removing the excess nitric acid in vacuo, pptg the product at —10° with eth, and recrystn from ethanol... [Pg.862]

The synthesis of 2,4,6-tris(trinitromethyl)-l,3,5-triazine (69) has been achieved for the first time by nitration of the corresponding tris(dicarboxymethyl) compound, obtained by hydrolysis of the hexa-f-butyl ester. Nitration of the hexa-methyl or -ethyl esters gave (69). The trinitromethyl group undergoes ready displacement by nucleophiles (Scheme 26) [95MC17],... [Pg.268]

Category 1 is by far the largest. It includes nitro groups, both aliphatic and aromatic nitrate esters nitrate salts nitramines and nitrosamines. Nearly all of the explosives listed in Table 37.3 fall into this category. Prominent examples are nitromethane, an... [Pg.1752]

Structure of cellulose polymer and determination of molecular weight Pyrolysis of nitrocellulose Thcrmochemical properties of nitrocellulose Mixed esters nitrates and sulphates Stabilization of nitrocellulose Knccht compound Manufacture of nitrocellulose Semi-continuous methodof Bofors-Nobel-Chematur Drying of nitrocellulose Safety in the manufacture of nitrocellulose Starch nitrates (nitrosiarch)... [Pg.8]

Hydrazine nitrace Fluoiine nitrate Mcthylamine nitrate Tetramethylammonium nitrate Guanidine nitrate Properties Manufacture Urea nitrate Thiourea nitrate Ethylene diamine dinitritc Hexamethylenetetramine diniirate Nitrates of ethanolamine nitric esters Ethanolamine nitric ester nitrate (ethanolamine dinitrate) Diethanolamine dinitric ester nitrate (diethanolamine trinitrate) Trictham amine trimtnc ester nitrate (triethanolamine tetranitrate) Oxontum nitrate Literature... [Pg.346]

Formation of nitrate esters GaS chromatography of alkyl nitrates Alkenes as a source of nitrate esters Nitrate esters asexplosives Biological action of nitrate esters Glycerol trinitrate (nitroglycerine)... [Pg.358]

Pyrometallurgical operations open-hearth steel furnace reaction of dinitrochlorobenzene removal of mercaptans from petroleum fractions alkaline hydrolysis of esters nitration of aromatic compounds nitration of higher olefins liquid-liquid reactions in phosphorous chemistry special case measurement of the solubility of A in the B phase. [Pg.787]

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