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Equation linearized frequency

The nondimensionalized frequencies are related to linear and angular frequencies by equation 3.36. The conversion factor from linear frequencies in cm to undimension-alized frequencies is chik = 1.4387864 cm (where c is the speed of hght in vacuum). Acoustic branches for the various phases of interest may be derived from acoustic velocities through the guidelines outlined by Kieffer (1980). Vibrational modes at higher frequency may be derived by infrared (IR) and Raman spectra. Note incidentally that the tabulated values of the dispersed sine function in Kieffer (1979c) are 3 times the real ones (i.e., the listed values must be divided by 3 to obtain the appropriate value for each acoustic branch see also Kieffer, 1985). [Pg.141]

Each frequency track has a birth and death index and dt such that bt denotes the first DFT block at which f0i is present ( active ) and d, the last (each track is then continuously active between these indices). Frequencies are expressed on a log-freuency scale, as this leads to linear estimates of the pitch curve (see [Godsill, 1993] for comparison with a linear-frequency scale formulation). The model equation for the measured log-frequency tracks fa[n is then ... [Pg.391]

A phase difference between the carrier frequency and the pulse leads to a phase shift which is almost the same for all resonance frequencies (u)). This effect is compensated for by the so-called zero-order phase correction, which produces a linear combination of the real and imaginary parts in the above equation with p = po- The finite length of the excitation pulse and the unavoidable delay before the start of the acquisition (dead time delay) leads to a phase error varying linearly with frequency. This effect can be compensated for by the frequency-dependent, first-order phase correction p = Po + Pi((o - (Oo), where the factor p is frequency dependent. Electronic filters may also lead to phase errors which are also almost linearly frequency-dependent. [Pg.130]

A plot of In F(C) versus /T yields the required slope d In F(C)/d T K This curve is nearly linear over the temperature intervals normally encountered in thennogravimetric decomposition analysis. Equation 3-26 is not a direct solution for the activation energy because d In p(j )/dr is a funciton of as well as of T. However by choosing a trial value of X (e. g. 40) a first approximation of E can be calculated using equation 3-26. Better values of E are then obtained by iteration of the same equation. The frequency (pre-exponential) factor A can be derived directly from equation 3-23 at each data point once E is known. [Pg.75]

Nuclei with magnetic moments precess in static magnetic fields at frequencies proportional to the local static magnetic field strength. Let represent the static magnetic field strength, let y represent a proportionality constant called the magnetogyric ratio, and let the radian precession frequency be (= 2i, where /is the linear frequency of precession). Then the relationships between these quantities may be expressed mathematically as the Larmor equation ... [Pg.617]

The fact that the ratio of the slopes of the two linear frequency curves is equal to the ratio of the initial slopes of the yield curves is evident from equation (16) that these are in turn equal to the ratio of the corresponding integrals of Y z) is evident from equation (17) and that all are equal to the ratio of the corresponding values of Fmax is evident from equation (18). Thus, accurate measurements of Fmax can be used to determine RMEs under the conditions stated in the preceding definition. [Pg.293]

If the speetral function of the dissipation from the system, y( ), is known, the deviation speetral density, (xx)qj, can be derived direetly from Eqs (4) and (5). For example, if we consider the linear frequency dependence of the friction function Xffl) = 7c equation tranforms into ... [Pg.412]

Instability is a nonlinear phenomenon. However, the dynamic behavior of nuclear reactors can be assumed to be linear for small perturbations around steady-state conditions. This allows the reactor stability to be studied and the threshold of instability in nuclear reactors to be predicted by using a linear model and solving linearized equations. Linear stability analyses in the frequency domain have been... [Pg.28]

Note the presence of the ra prefactor in the absorption spectrum, as in equation (Al.6.87) again its origm is essentially the faster rate of the change of the phase of higher frequency light, which in turn is related to a higher rate of energy absorption. The equivalence between the other factors in equation (Al.6.110) and equation (Al.6.87) under linear response will now be established. [Pg.258]

In this section we discuss the frequency spectrum of excitations on a liquid surface. Wliile we used linearized equations of hydrodynamics in tire last section to obtain the density fluctuation spectrum in the bulk of a homogeneous fluid, here we use linear fluctuating hydrodynamics to derive an equation of motion for the instantaneous position of the interface. We tlien use this equation to analyse the fluctuations in such an inliomogeneous system, around equilibrium and around a NESS characterized by a small temperature gradient. More details can be found in [9, 10]. [Pg.725]

The Bloch equation approach (equation (B2.4.6)) calculates the spectrum directly, as the portion of the spectrum that is linear in a observing field. Binsch generalized this for a frilly coupled system, using an exact density-matrix approach in Liouville space. His expression for the spectrum is given by equation (B2.4.42). Note that this is fomially the Fourier transfomi of equation (B2.4.32). so the time domain and frequency domain are coimected as usual. [Pg.2104]

The detector must be sensitive to the radiation falling on it, and the spectrum is very often displayed on a chart recorder. The spectrum may be a plot of absorbance or percentage transmittance (IOO///0 see Equation 2.16) as a function of frequency or wavenumber displayed linearly along the chart paper. Wavelength is not normally used because, unlike frequency and wavenumber, it is not proportional to energy. Wavelength relates to the optics rather than the spectroscopy of the experiment. [Pg.43]

This is an identical expression to fhaf for a diatomic or linear polyatomic molecule (Equations 5.11 and 5.12) and, as fhe rofational selection mle is fhe same, namely, AJ = 1, fhe fransifion wavenumbers or frequencies are given by... [Pg.118]

I When the system voltage is linear (an ideal condition that would seldom exist) but the load is non-linear The current will be distorted and become non-sinusoidal. The actual current /, (r.m.s.) (equation (23.2)) will become higher than could be measured by an ammeter or any other measuring instrument, at the fundamental frequency. Figure 23.13 illustrates the difference between the apparent current, measured by an instrument, and the actual current, where / = active component of the current... [Pg.744]

L. Mandelstam and N. Papalexi performed an interesting experiment of this kind with an electrical oscillatory circuit. If one of the parameters (C or L) is made to oscillate with frequency 2/, the system becomes self-excited with frequency/ this is due to the fact that there are always small residual charges in the condenser, which are sufficient to produce the cumulative phenomenon of self-excitation. It was found that in the case of a linear oscillatory circuit the voltage builds up beyond any limit until the insulation is ultimately punctured if, however, the system is nonlinear, the amplitude reaches a stable stationary value and oscillation acquires a periodic character. In Section 6.23 these two cases are represented by the differential equations (6-126) and (6-127) and the explanation is given in terms of their integration by the stroboscopic method. [Pg.381]

Equation (73) is based on the observed shift in vibrational frequency. Since these measurements are usually carried out at a level of stress which is well below the theoretical breaking strength of the chain, they may correspond to the initial portion of the curve in Fig. 20 which also predicts a linear decrease of U(a) on the level of stress. [Pg.112]

What does tins equation tell us Because the kinetic energy of the ejected electrons varies linearly with frequency, a plot of the kinetic energy against the frequency of the radiation should look like the graph in Fig. 1.17, a straight line of slope h, the same for all metals, and have an extrapolated intercept with the vertical axis at — horizontal axis (corresponding to zero kinetic energy of the ejected electron) is at fI>/6 in each case. [Pg.135]


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