Enzymatic synthesis ionic liquids/supercritical carbon dioxide

Reetz, M.T., W. Wiesenhofer, G. Francio and W. Leitner, Continuous Flow Enzymatic Kinetic Resolution and Enantiomer Separation Using Ionic Liquid/Supercritical Carbon Dioxide Media, Advanced Synthesis Catalysis, 345, 1221-1228 (2003). 

Hernandez FJ, de los Rios AP, Gomez D, Rubio M, ViUora G. A new recirculating enzymatic membrane reactor for ester synthesis in ionic liquid/supercritical carbon dioxide biphasic systems. Appl Catal B 2006 67 121-126. 

Ionic Liquids/Supercritical Carbon Dioxide as Advantageous Biphasic Systems in Enzymatic Synthesis... 

Hernandez, F. J., A. P. de los Rfos, D. Gomez, M. Rubio, and G. Vfllora. 2006. A New Recirculating Enzymatic Membrane Reactor for Ester Synthesis in Ionic Liquid/ Supercritical Carbon Dioxide Biphasic Systems. Applied Catalysis B Environmental Cl (1-2) 121-126. 

P. Lozano,. M. Bernal, M. Vaultier, Towards continuous sustainable processes for enzymatic synthesis of biodiesel in hydrophobic ionic liquids/supercritical carbon dioxide biphasic systems, Fuel 90 (2011) 3461-3467. 

Fig. 8.1 Experimental set-up of the recirculating enzymatic membrane reactor used for the synthesis of butyl propionate from vinyl propionate and 1-butanol catalysed by Candida antarctica lipase B in supercritical carbon dioxide and supercritical carbon dioxide/ionic liquid biphasic system [17]...

Mori T, Kobayashi A, Okahata Y (1998) Biocatalytic esterification in supercritical carbon dioxide using a Upid-coated lipase. Chem Lett 9 921-922 Mori M, Gomez Garcia R, BeUeviUe MP (2005) A new way to conduct enzymatic synthesis in an active membrane using ionic liquids as catalyst support. Catal Today 104 313-317 Morley KL, Kazlauskas RJ (2005) Improving enzyme properties when are closer mutations better TIBTECH 23(5) 231-237... 

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