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Energy work relationship

Within the context of its application to solving practical problems, thermodynamics is primarily concerned with systems at equilibrium. From an observational viewpoint, a system is at equilibrium if its properties do not change with time when it is isolated from its surroundings. The concept of equilibrium is a unifying principle that determines energy-work relationships as well as phase relationships. [Pg.2]

The finite-element method has been used extensively for the evaluation of slope stability (primarily for terrestrial soil but it has also been used for marine soils). The basic methodology utilized is based on the original work by Wilson (1965). The method itself is based on the determination of the resulting deformations of a frame imder an imposed load. The deformations are based on the minimum potential energy. The relationship between the deformations q and the loads QJ is given by the following expression. [Pg.467]

Linear Free-Energy and Related Mathematical Models (2) Polarizability Models and, (3) Quantum Chemical Models. These methods differ in the level of theoretical sophistication needed to obtain a working relationship, but all presently rely heavily on the use of multiple regression techniques in relating observed biological activities to a given mathematical model. [Pg.245]

In the previous section, work was calculated by integrating a force over the distance through which it acts. Work can also be derived from an energy balance relationship. While this produces the same outcome and is therefore a redundant step, it provides an additional insight and helps in the understanding of the mechanism. [Pg.59]

Area X in the figure represents the friction work Area Y represents the work done by the lower tension during the change in strain. The work-energy balance relationship can... [Pg.59]

The product of thermodynamic forces and fiows yields the rate of entropy production in an irreversible process. The Gouy-Stodola theorem states that the lost available energy (work) is directly proportional to the entropy production in a nonequilibrium phenomenon. Transport phenomena and chemical reactions are nonequilibrium phenomena and are irreversible processes. Thermodynamics, fiuid mechanics, heat and mass transfer, kinetics, material properties, constraints, and geometry are required to establish the relationships... [Pg.177]

From the definitions of Wa and Wq, it can be seen that is a function of surface energies. If the structure of a material and the molecular potential energy-separation relationships are known, the surface energy can be calculated by evaluating the work required to separate to infinity the material either side of a chosen plane. For a material in which the dominant intermolecular forces are dispersion force interactions, the Lennard-Jones potential (see Dispersion forces and Polar forces) will apply, and the calculation is relatively simple. It gives work of cohesion on phase 1... [Pg.218]

Thermodynamics Science dealing with the relationships between energy, work, and the properties of matter. Thermodynamics defines the best performance that can be achieved with power conversion, generation, and heat transfer systems. [Pg.1178]

With these quantities, the predicted lifetime of corresponding bondons, obtained from the working expressions for bondonic mass and velocity working through the basic time-energy Heisenberg relationship, is here restrained at the level of kinetic energy only for the bondonic particle thus, one yields the subsequent analytical forms ... [Pg.23]

Surface ionization. Takes place when an atom or molecule is ionized when it interacts with a solid surface. Ionization occurs only when the work function of the surface, the temperature of the surface, and the ionization energy of the atom or molecule have an appropriate relationship. [Pg.439]

Basically, Newtonian mechanics worked well for problems involving terrestrial and even celestial bodies, providing rational and quantifiable relationships between mass, velocity, acceleration, and force. However, in the realm of optics and electricity, numerous observations seemed to defy Newtonian laws. Phenomena such as diffraction and interference could only be explained if light had both particle and wave properties. Indeed, particles such as electrons and x-rays appeared to have both discrete energy states and momentum, properties similar to those of light. None of the classical, or Newtonian, laws could account for such behavior, and such inadequacies led scientists to search for new concepts in the consideration of the nature of reahty. [Pg.161]


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See also in sourсe #XX -- [ Pg.226 , Pg.227 , Pg.228 , Pg.229 , Pg.230 ]




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