Energy values large radii

Respective corrections to the energy levels in deuterium are even much larger than in hydrogen due to the large radius of the deuteron. The nuclear size contribution of order (Za) to the 2S — IS splitting in deuterium is equal to (we have used in this calculation the value of the deuteron charge radius obtained in [44] from the analysis of all available experimental data)... 

The low values for the Gibbs free energy and the enthalpy of solvation are attributed to the small dipole moment and the large radius of the PH3 molecule. The cations [P2HsPH3]+ and [P3H6PH3]+ can be observed at temperatures as high as 300 K [38]. 

This, therefore Is the fundamental problem with high surface-area electrochemical capacitors. In order to achieve the desired high energy densities, large surface-area materials must be used in a layer of finite thickness. This automatically ensures that an additional resistance associated with current penetration of the porous structure will be present. Whether this additional resistance interferes with a proposed application is a separate question. Obviously, since r is equal top/l a where p is the specific electrolyte resistance and a is the pore radius, then the greater the values of p and I and the smaller the pore radius, the more severe is the distributed resistance problem. 

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