Energy lead-acid

Chen, Y Hu, Y Hu, F. High specific energy lead acid batteries for electric vehicles. Faming Zhuanli Shenqing Gongkai Shuomingshu CN 1221991, 1999 Chem. Abstr. 2000,132, 336895. 

In the 1990s, the use of batteries in electric vehicles and for load leveling is being revived partly for environmental reasons and partly because of scarce energy resources. Improvements in battery performance and life, fewer maintenance requirements, and automatic control systems are making these appHcations feasible. Research and development is ongoing all over the world to develop improved lead—acid batteries as weU as other systems to meet these needs. 

The Na—S battery couple is a strong candidate for appHcations ia both EVs and aerospace. Projected performance for a sodium—sulfur-powered EV van is shown ia Table 4 for batteries having three different energies (68). The advantages gained from usiag a Na—S system rather than the conventional sealed lead—acid batteries are evident. 

The energy costs of building vehicles must also be considered. For ICE vehicles, more energy is usually used in construction of the vehicle than -will be consumed in fuel for driving 100,000 miles. For the EV, the dynamics are even worse since the material and energy costs of batteries are considerable. Batteries are expensive since they entail a substantial amount of material (added weight) and often involve multiple complex construction. For example, the thirty-two advanced lead-acid batteries for the 1995 GM Impact weighed over 850 pounds. 

Both our original prediction about the effect of ionization energy on acid-base behavior and the trend which we have observed in the first three elements lead us to expect that the hydroxide or oxide of silicon should not be basic, but perhaps should be weakly acidic. This is in fact observed. Silicon dioxide, Si02, can exist as a hydrated solid containing variable amounts of water,... 

It is also useful here to compare the energy stored in the lead-acid battery. A standard 12 V battery may be able to deliver 10 A of current for 4 hr, for a total of 480 W-hr. This amounts to 1632 Btu, which is sufficient to raise 10 lb of catalysts by only 580°F, over the course of four hours. 

The thermodynamic properties of magnesium make it a natural choice for use as an anode material in rechargeable batteries, as it may provide a considerably higher energy density than the commonly used lead-acid and nickel-cadmium systems, while in contrast to Pb and Cd, magnesium is inexpensive, environmentally friendly, and safe to handle. However, the development of Mg-ion batteries has so far been limited by the kinetics of Mg " " diffusion and the lack of suitable electrolytes. Actually, in spite of an expected general similarity between the processes of Li and Mg ion insertion into inorganic host materials, most of the compounds that exhibit fast and reversible Li ion insertion perform very poorly in Mg " ions. Hence, there... 

In 1899, the nickel-cadmium battery, the first alkaline battery, was invented by a Swedish scientist named Waldmar Jungner. The special feature of this battery was its potential to be recharged. In construction, nickel and cadmium electrodes in a potassium hydroxide solution, it was the first battery to use an alkaline electrolyte. This battery was commercialized in Sweden in 1910 and reached the Unites States in 1946. The first models were robust and had significantly better energy density than lead-acid batteries, but nevertheless, their wide use was limited because of the high costs. 

The first difference between these two batteries is the voltage they produce a watch battery produces about 3 V and a lead-acid cell about 2 V. The obvious cause of the difference in emf are the different half-cells. The electrode potential E is the energy, expressed as a voltage, when a redox couple is at equilibrium. 

These batteries are much cheaper to make than earlier nickel battery types, and have an energy density almost double that of lead-acid. NiMH batteries can accept three times as many charge cycles as lead-acid, and work better in cold weather. NiMH batteries have proven effective in laptop computers, cellular phones, and video cameras. 

NiMH batteries can power an electric vehicle for over 100 miles, but are still several times more expensive than lead-acid. NiMH batteries from Energy Conversion Devices were installed in GM s EVj and S-10 electric pickup truck, doubling the range of each. Chrysler has also used... 

Other battery technologies include sodium-sulfur which was used in early Ford EVs, and zinc-air. Zinc appeared in GM s failed Electrovette EV in the late 1970s. Zinc-air batteries have been promoted by a number of companies, including Israel s Electric Fuel, Ltd. Zinc is inexpensive and these batteries have six times the energy density of lead-acid. A car with zinc-air batteries could deliver a 400 mile range, but the German postal service found that these batteries cannot be conventionally recharged. 

---