Encapsulated polymer blend technique

The polymer blends were prepared by solution blending and freeze drying. The solvent-free freeze dried powders were subsequently compression molded and cut into DMA-sized pieces for analysis. Keinath has successfully used the polymer blending technique coupled with the negative second derivative data treatment to characterize the Tp, Tg, and Tn transitions in a scries of eight different poly( -alkyl methaciylate)s encapsulated in a continuous matrix of poly(dimethyl jrfiraiylene oxide). ... 

The crosslinking technique forms a PFB/F8BT bilayer with a well-defined interface, and was shown to have a negligible effect on the transport properties as well as the PL and EL emission spectra of the PFB [61], Single-layer, PFB-only and polymer blend LEDs were produced by spin coating 170-nm films from common chloroform solution onto a PEDOTPSS / ITO substrate. For all devices, cathodes were formed by thermal evaporation of Ca (60 nm) and encapsulated with a thick A1 overlayer. 

Thermal methods include differential scaiming calorimetry, thermomechanical analysis, hot stage microscopy, and a new technique referred to as "photo DSC." Two dynamic mechanical analysis techniques have been developed, the first employing a perforated shim stock support, and the second utilizing polymer blend encapsulation. 

Over the past several years we have applied dynamic mechanical analysis to the study of the polymer liquid state. The principal requirement in being able to use DMA in this respect is to provide some means of support for the liquid phase material through temperatures well above its Tg (or T ) softening point range. Two techniques have been developed and will be reported on here. The first technique employs a perforated shim support upon which samples are coated. " The second technique utilizes a polymer blend encapsulation scheme to isolate liquid material droplets in a higher Tg continuous phase matrix. ... 

IL-dissolved cellulose can easily be reconstituted in water in controlled architectures (fibers, membranes, beads, fiocs, etc.) using conventional extrusion spinning or forming techniques. By incorporating functional additives into the solution before reconstitution. Professor Rogers can prepare blended or composite materials. The incorporated functional additives can be either dissolved (e.g., dyes, complexants, other polymers) or dispersed (e.g., nanoparticles, clays, enzymes) in the IL before or after dissolution of the cellulose. With this simple, noncovalent approach, one can readily prepare encapsulated cellulose composites of tunable architecture, functionality, and rheology. 

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