Electroplating, parts

PC/ABS Cycoloy/Borg-Wamer Chemicals Improved no-load heat resistance, impact strengdi Electroplated parts, grilles, wheel covers, pliances, instrument panels, telecommunications... 

Uses photography toning solutions electroplating parts of clocks and watches detecting carbon monoxide leaks in buried gas pipes ... 

The Electro-Coatings case study describes how the above principles were applied to a focal firm that produces electroplated parts for the automotive industry. 

Outgassing from electroplated parts can be a problem because of outgassing of hydrogen and organic additives. 

A fused-Sn plating is one that has been reflowed (melted and resolidified) subsequent to electroplating. Typically, an electroplated part is dipped into a hot-oil bath and held at a temperature above the melting point of Sn. The objective of the fusing operation is to allow the Sn to slowly sohdify and, thereby, remove any internal stresses that may have resulted from the electrodeposition process. Fused Sn is reputed to not grow whiskers unless the surface of the tin is scratched, compressively stressed, or plastically deformed [2]. 

Type 2 tlie inliibiting species takes part in tlie redox reaction, i.e. it is able to react at eitlier catliodic or anodic surface sites to electroplate, precipitate or electropolymerize. Depending on its activation potential, tlie inliibitor affects tlie polarization curve by lowering tlie anodic or catliodic Tafel slope. 

The concentration of cyanide, CN, in a copper electroplating bath can be determined by a complexometric titration with Ag+, forming the soluble Ag(CN)2 complex. In a typical analysis a 5.00-mL sample from an electroplating bath is transferred to a 250-mL Erlenmeyer flask, and treated with 100 mL of H2O, 5 mL of 20% w/v NaOH, and 5 mL of 10% w/v Kl. The sample is titrated with 0.1012 M AgN03, requiring 27.36 mL to reach the end point as signaled by the formation of a yellow precipitate of Agl. Report the concentration of cyanide as parts per million of NaCN. 

Part 403 general pretreatment regulations for existing and new sources of pollution Part 411 cement manufacturing point source category Part 413 electroplating point source category... 

Potassium cyanide [151 -50-8] KCN, a white crystalline, deUquescent soHd, was initially used as a flux, andlater for electroplating, which is the single greatest use in the 1990s. The demand for potassium cyanide was met by the ferrocyanide process until the latter part of the nineteenth century, when the extraordinary demands of the gold mining industry for alkah cyanide resulted in the development of direct synthesis processes. When cheaper sodium cyanide became available, potassium cyanide was displaced in many uses. With the decline in the use of alkah cyanides for plating the demand for potassium cyanide continues to decline. The total world production in 1990 was estimated at about 4500 t, down from 7300 t in 1976. 

Cladding may be less expensive than selective electro deposition when coatings greater than 1 p.m of a noble metal are required, but may be more expensive than electro deposition for thinner coatings. Selective techniques are most easily used for sheet metal substrates that are to be machine stamped and formed into contacts. Clad noble metals are considerably more ductile (and less hard) than comparable electro deposits and, therefore, are better suited to forming operations. Contacts that are made into separate parts from rod by screw machining are usually coated on all exposed surfaces by barrel electroplating. 

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