Electron orbit transition

In Bohr s atomic model, what electron orbit transition produces the blue-green line in hydrogen s atomic emission spectmm ... 

For hydrogen s Balmer series, electron orbit transitions occur from larger orbits to the n = 2 orbit that is, nf = 2. 

Calculate the wavelengths for the following electron orbit transitions. 

Extend the Bohr model by calculating the wavelength and energy per quantum for the electron orbit transition for which nf= 3 and n, = 5. This transition accounts for a spectral line in hydrogen s Paschen series. 

Electron Transition According to the Bohr model shown in Figure 5.23, what type of electron-orbit transitions produce the ultraviolet lines in hydrogen s... 

Atomic vapor-absorption bands can be used to produce a high-performance notch filter [57-65]. As its name suggests, this type of filter relies on the absorption of specific wavelengths by electron orbital transitions in an atomic vapor. The filter is based on a metal vapor (e.g., rubidium [65]), which is often held in a transparent glass cell. Such filters can produce fair attenuation (3-5 optical density) over a very narrow bandwidth (less than 1 cm ) [63]. Their principal drawbacks are their relative complexity, their many closely spaced absorption peaks that can interfere with the data of interest, and the fact that the absorption peaks are not necessarily coincident with common laser wavelengths. Because the filter s absorption bands are so extremely narrow, if the laser shifts frequency even minutely, it will fall outside the absorption peak and will not be blocked. These challenges reduce the general applicability and attractiveness of this type of filter for Raman systems. 

Most electronic valence transitions shift to longer wavelengths at higher pressures drat is, the gap between the highest occupied orbital and lowest unoccupied orbital tends to decrease upon compression. The rates of shift usually are larger (1) for pure materials than for solutes in a solvent and (2) for stronger (more allowed) transitions. However, these correlations are not quantitative, and many transitions shift in the opposite... 

UV-VIS Aldehydes and ketones have two absorption bands in the ultraviolet region Both involve excitation of an electron to an antibonding tt orbital In one called a TT TT transition the electron is one of the tt electrons of the C=0 group In the other called an n ir transition it is one of the oxygen lone pair electrons Because the tt electrons are more strongly held than the lone parr electrons the transition is of... 

Shorter-wavelength radiation promotes transitions between electronic orbitals in atoms and molecules. Valence electrons are excited in the near-uv or visible. At higher energies, in the vacuum uv (vuv), inner-shell transitions begin to occur. Both regions are important to laboratory spectroscopy, but strong absorption by make the vuv unsuitable for atmospheric monitoring. Electronic transitions in molecules are accompanied by stmcture... 

Optical absorption measurements give band-gap data for cubic sihcon carbide as 2.2 eV and for the a-form as 2.86 eV at 300 K (55). In the region of low absorption coefficients, optical transitions are indirect whereas direct transitions predominate for quantum energies above 6 eV. The electron affinity is about 4 eV. The electronic bonding in sihcon carbide is considered to be predominantiy covalent in nature, but with some ionic character (55). In a Raman scattering study of vahey-orbit transitions in 6H-sihcon carbide, three electron transitions were observed, one for each of the inequivalent nitrogen donor sites in the sihcon carbide lattice (56). The donor ionization energy for the three sites had values of 0.105, 0.140, and 0.143 eV (57). 

Color from Transition-Metal Compounds and Impurities. The energy levels of the excited states of the unpaked electrons of transition-metal ions in crystals are controlled by the field of the surrounding cations or cationic groups. Erom a purely ionic point of view, this is explained by the electrostatic interactions of crystal field theory ligand field theory is a more advanced approach also incorporating molecular orbital concepts. 

Metals and alloys, the principal industrial metalhc catalysts, are found in periodic group TII, which are transition elements with almost-completed 3d, 4d, and 5d electronic orbits. According to theory, electrons from adsorbed molecules can fill the vacancies in the incomplete shells and thus make a chemical bond. What happens subsequently depends on the operating conditions. Platinum, palladium, and nickel form both hydrides and oxides they are effective in hydrogenation (vegetable oils) and oxidation (ammonia or sulfur dioxide). Alloys do not always have catalytic properties intermediate between those of the component metals, since the surface condition may be different from the bulk and catalysis is a function of the surface condition. Addition of some rhenium to Pt/AlgO permits the use of lower temperatures and slows the deactivation rate. The mechanism of catalysis by alloys is still controversial in many instances. 

Equation (5-69) is an important result. It was first obtained by Marcus " in the context of electron-transfer reactions. Marcus derivation is completely different from the one given here. In electron transfer from one molecule (or ion) to another, no bonds are broken or formed, so the transition state theory does not seem to be applicable. Marcus assumed negligible orbital overlap in the electron-transfer transition state, but he later obtained the same equation for group transfer reactions requiring significant overlap. Many applications have been made to proton transfers and nucleophilic displacements. ... 

Bahn, /. way, road, track path orbit trajectory railway breadth (of cloth), bahnbrechend, p.a. pioneer, epoch-making. Bahn-brecher, m. pioneer, -durchmesser, m. orbital diameter, -ebene, /. orbital plane, -elektron, n. orbital electron, bahnen, v.t. beat, smooth, clear (a way). Bahn-hof, m. (railway) station, -impuls, m. linear momentum orbital moment, -sdileife, -schlinge, /., orbital loop, -spur, /, track, -tibergang, m. orbital transition, -zug, m. railway train. 

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