LEED electrons

Exvz = kinetic energy of Auger electron LEED = low energy electron diffraction... 

Stipp, S. L. Hochella, M. F. Jr. (1991). Structure and bonding environments at the calcite surface as observed with X-ray photoelectron spectroscopy (XPS) and low energy electron (LEED) diffraction. Geochimica et Cosmochimica Acta, 55, 1723-1736. 

LEED See low energy electron dilTraction. lei See chelate effect, iepargylic acid See azeleic acid. 

Experimentally, it is common for LEED and Auger capabilities to be combined the basic equipment is the same. For Auger measurements, a grazing angle of incident electrons is needed to maximize the contribution of surface... 

Fig. VIII-10. (a) Intensity versus energy of scattered electron (inset shows LEED pattern) for a Rh(lll) surface covered with a monolayer of ethylidyne (CCH3), the structure of chemisorbed ethylene, (b) Auger electron spectrum, (c) High-resolution electron energy loss spectrum. [Reprinted with permission from G. A. Somoijai and B. E. Bent, Prog. Colloid Polym. ScL, 70, 38 (1985) (Ref. 6). Copyright 1985, Pergamon Press.]...

The relative intensity of a certain LEED diffraction spot is 0.25 at 300 K and 0.050 at 570 K using 390-eV electrons. Calculate the Debye temperature of the crystalline surface (in this case of Ru metal). 

LEED Low-energy electron diffraction [62, 75, 105] Elastic backscattering of electrons (10-200 eV) Surface structure... 

ESDIAD Electron-stimulated desorption ion angular distribution [150-152] A LEED-like pattern of ejected ions is observed Orientation of adsorbed species... 

The technique of low-energy electron diffraction, LEED (Section VIII-2D), has provided a considerable amount of information about the manner in which a chemisorbed layer rearranges itself. Somotjai [13] has summarized LEED results for a number of systems. Some examples are collected in Fig. XVlII-1. Figure XVIII-la shows how N atoms are arranged on a Fe(KX)) surface [14] (relevant to ammonia synthesis) even H atoms may be located, as in Fig. XVIII-Ih [15]. Figure XVIII-Ic illustrates how the structure of the adsorbed layer, or adlayer, can vary wiA exposure [16].f There may be a series of structures, as with NO on Ru(lOTO) [17] and HCl on Cu(llO) [18]. Surface structures of... 

We will, in the latter part of this discussion, focus only on those few methods that have been the most productive, with low-energy electron diffraction (FEED) receiving the most attention. Indeed, LEED has been the most successfiil surface stmctiiral method in two quite distinct ways. First, LEED has become an almost universal characterization... 

As the table shows, a host of other teclmiques have contributed a dozen or fewer results each. It is seen that diffraction teclmiques have been very prominent in the field the major diffraction methods have been LEED, PD, SEXAFS, XSW, XRD, while others have contributed less, such as NEXAFS, RHEED, low-energy position diffraction (LEPD), high-resolution electron energy loss spectroscopy (HREELS), medium-energy electron diffraction (MEED), Auger electron diffraction (AED), SEELFS, TED and atom diffraction (AD). 

The diffraction pattern observed in LEED is one of the most connnonly used fingerprints of a surface structure. Witii XRD or other non-electron diffraction methods, there is no convenient detector tliat images in real time the corresponding diffraction pattern. Point-source methods, like PD, do not produce a convenient spot pattern, but a diffrise diffraction pattern that does not simply reflect the long-range ordermg. 

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