Electrical Conductivity and Dielectric Loss

Electrical properties of glass ceramics are determined by the properties of both the crystalline phases and the residual glass. Electrical conductivity and dielectric loss (at low frequencies) are dominated by the concentration and mobility of alkali ions in the glass phase. The dielectric constant is dominated by the crystalline phase, especially when that phase consists of high dielectric constant materials such as ferroelectric crystals. The... 

The high thermal conductivity of BeO combined with other properties make it a unique material. The mode of heat transfer is by lattice waves, since the eleetrons are tightly bonded to the ions. The lack of free electrons causes the electrical conductivity and dielectric loss to be low. This combination of high thermal conductivity and low electrical conductivity is unique among commercially available materials that are economically feasible for most applications. 

See lext. XD = X-ray diffraction 1R = infrared spectrum R = Raman spectrum UV = ultraviolet spectrum H-NMR = ]HNMR spectrum C-NMR = 13CNMR spectrum F-NMR =, 9FNMR spectrum MS = mass spectrum PES — photoelectron spectrum E - electric polarization and dielectric loss measurements D = dipole moment measurements TDPAC = time differential perturbed angular correlation measurements GC = gas chromatography TA = thermal analysis M = molecular weight A = electrical conductance. c Isolated as the THF adduct M(dik)Cl3-C4HgO. 

Method involves placing a specimen between parallel plate capacitors and applying a sinusoidal voltage (frequencies ranging from 1 mHz to 1 MHz) to one of the plates to establish an electric field in the specimen. In response to this field, a specimen becomes electrically polarized and can conduct a small charge from one plate to the other. Through measurement of the resultant current, the dielectric constant and dielectric loss constant for a specimen can be measured. The sharp increases in both the dielectric constant and the dielectric loss constant during a temperature scan are correlated with the occurrence of Tg... 

The electrical properties of materials are important for many of the higher technology applications. Measurements can be made using AC and/or DC. The electrical properties are dependent on voltage and frequency. Important electrical properties include dielectric loss, loss factor, dielectric constant, conductivity, relaxation time, induced dipole moment, electrical resistance, power loss, dissipation factor, and electrical breakdown. Electrical properties are related to polymer structure. Most organic polymers are nonconductors, but some are conductors. 

DIELECTRIC THEORY. A dielectric is a material having electrical conductivity low in comparison to that of a metal. It is characterized by its dielectric constant and dielectric loss, both of which are functions of frequency and temperature. The dielectric constant is the ratio of the strength of an electric held in a vacuum to that in the dielectric for the same distribution of charge. It may also be defined and measured as the ratio of the capacitance C of an electrical condenser filled with the dielectric to the capacitance Cu of the evacuated condenser ... 

Electrical conductivity, permittivity (dielectric constant) and loss angle are the most important electrical properties of glass at low temperatures. These properties are important when glass is used as an insulating material or as a functional component of electrotechnical devices and instruments. 

The electrical properties of interest for ceramics include conductivity, resistivity, dielectric breakdown strength, dielectric constant, loss factor, and electromechanical coupling. Most ceramics do not have high electrical conductivity, and thus ceramics have found application as electrical insulators for many years. The electrical insulating capability of some ceramics is also retained under high electric field this is referred to as high dielectric breakdown strength... 

The dielectric permittivity of a medium (relative to the permittivity of free space, 8q = 8.85 X 10 F/m) is given by e and measures the polarization of the medium per unit applied electric field. The dielectric loss factor arises from energy loss during time-dependent polarization and bulk conduction. The loss factor is written as a". The loss tangent or dissipation of the medium, tan<5 is defined by e"/e. The orientation of molecular dipoles has a characteristic time r. Typically is short early in the cure but grows large at the end of the cure. 

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