Effective spin limit

Another approach to this problem is a search for the other more effective spin traps. Frejaville et al. [23] demonstrated that the half-life of spin-adduct of superoxide with 5-(diethoxyphosphoryl)-5-mcthyl-l -pyrrolinc-/V-oxide (DEMPO) is about tenfold longer than that of DMPO OOH. Despite a much more efficiency of this spin trap, its hydrophilic properties limit its use for superoxide detection in lipid membranes. Stolze et al. [24] studied the efficiency of some lipophilic derivatives of DEMPO in the reaction with superoxide. These authors demonstrated a higher stability of superoxide spin-adducts with 5-(di- -propoxypho-sphoryl)-5-methyl-1 -pyrrolinc-A -oxidc (DPPMPO) and 5-(di- -butoxyphosphoryl)-5-methyl-... 

One of the mayor drawbacks is that only volatile and temperature-resistant compounds can be investigated. Gases are magnetized faster than liquids, because they have shorter spin-lattice relaxation times (T ), due to an effective spin rotation mechanism. Therefore, pulse repetition times in flow experiments can be in the range of 1 s and some dozen transients can be accumulated per separated peak. Nevertheless, the sample amounts used nowadays in capillary GC are far from the detection limit of NMR spectroscopy, and therefore the sensitivity is low or insufficient, due to the small number of gas molecules per volume at atmospheric pressure in the NMR flow cell. In addition, high-boiling components (> 100 °C) are not easy to handle in NMR flow probes and can condense on colder parts of the apparatus, thus reducing their sensitivity in NMR spectroscopy. 

When R is less than 0.1, the system is essentially frozen at the slow-exchange limit, and Eq. (10.1) predicts two sharp signals, one at vA, the other at vB (Figure 10.1, R = 0.10). The halfwidth of these signals (v /2 is the inverse of the effective spin-spin relaxation time. 

An important and frequently encountered result, often mistakenly taken as evidence for pure precession, is that, in the unique perturber, identical potential curve limit, the effective spin-rotation constant of the 2E+ state, jv, is equal to Py. This result is a direct consequence of the second-order perturbation theoretical definition of the contribution of a 2II state to the spin-rotation splitting in a 2E state (see Section 3.5.4) ... 

Linear density in Effective length Count range factor Spinning limit ... 

Fibre tensile properties have their own importance, however, long before they arc embodied in any end product. For example, the spinning limits illustrated in Section 3.1.2 take account only of fiber linear density and effective length. 

For quadnipolar nuclei, the dependence of the pulse response on Vq/v has led to the development of quadnipolar nutation, which is a two-dimensional (2D) NMR experiment. The principle of 2D experiments is that a series of FIDs are acquired as a fimction of a second time parameter (e.g. here the pulse lengdi applied). A double Fourier transfomiation can then be carried out to give a 2D data set (FI, F2). For quadnipolar nuclei while the pulse is on the experiment is effectively being carried out at low field with the spin states detemiined by the quadnipolar interaction. In the limits Vq v the pulse response lies at v and... 

Bond [Min. Eng. (London), 60(1), 63-64 (1968)] reviewed attempts to induce breakage without wastefuUy applying pressure and concluded that inherent practical limitations have been found for the following methods spinning particles, resonant vibration, electro-hydrauhe crushing, induction heating, sudden release of gas pressure, and chisel-effect breakers. For a review of more recent efforts, see edition 6 of this handbook. 

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