Echo sequence

To understand how the chemical shift and multiplicity information is separated, we need to reconsider the spin-echo sequence described earlier. 

Figure 4. Dependence of the integrated intensity on the length between pulses, T, in the solid spin echo sequence. C6De/(Cs,Na)X at 2.4 molecules/supercage and 283 K. SW = 500 kHz.

The intense water signal and the broad protein resonances were suppressed by a combination of continuous secondary Irradiation at the water frequency and the Hahn spin-echo sequence (0[90 x-t-180 y-t-collect]). 

Another approach to obtain spatially selective chemical shift information is, instead of obtaining the entire image, to select only the voxel of interest of the sample and record a spectrum. This method called Volume Selective spectroscopY (VOSY) is a ID NMR method and is accordingly fast compared with a 3D sequence such as the CSI method displayed in Figure 1.25(a). In Figure 1.25(b), a VOSY sequence based on a stimulated echo sequence is displayed, where three slice selective pulses excite coherences only inside the voxel of interest. The offset frequency of the slice selective pulse defines the location of the voxel. Along the receiver axis (rx) all echoes created by a stimulated echo sequence are displayed. The echoes V2, VI, L2 and L3 can be utilized, where such multiple echoes can be employed for signal accumulation. 

Figure 2.2.14 shows cross-sections of salmon acquired with a gradient echo sequence (TR = 30 ms, TE = 15 ms, slice thickness = 4 cm, image matrix = 128 x 128, total acquisition time = 3.84 s). For the female salmon, roe were clearly visualized as dark regions because the T2 is shorter than that of the surrounding tissues. For the male salmon, milt was observed instead of roe. However, the image intensity of the milt was similar to that of the surrounding tissues. 

The slice selection procedure can be combined with a number of pulse sequences to spatially resolve NMR parameters or to contrast the profiles with a variety of filters. The most commonly used acquisition schemes implemented to sample echo train decays are the CPMG [(jt/2)0—(Jt)90] or a multi-solid echo sequence [(jt/ 2)0-(jt/2)9o]. In these instances, the complete echo train can be fitted to determine... 

For the experiments in type C catalysts, the pellets were overfilled with cyclohexane and initially cooled to 230 K. They were then reheated in steps of 1 K and allowed to equilibrate for 10 min before each measurement. The signal was determined from 32 accumulations with an echo sequence of 20 ms echo time to ensure that the signal from the plastically crystalline phase of cyclohexane had decayed fully. The typical heating curves of cyclohexane in the fresh and coked catalyst are displayed in Figure 3.3.3(a) As the temperature is increased, larger and... 

The reference scan is to measure the decay due to spin-lattice relaxation. Compared with the corresponding stimulated echo sequence, the reference scan includes a jt pulse between the first two jt/2 pulses to refocus the dephasing due to the internal field and the second jt/2 pulse stores the magnetization at the point of echo formation. Following the diffusion period tD, the signal is read out with a final detection pulse. The phase cycling table for this sequence, including 2-step variation for the first three pulses, is shown in Table 3.7.2. The output from this pair of experiments are two sets of transients. A peak amplitude is extracted from each, and these two sets of amplitudes are analyzed as described below. 

Fig. 4.1.5 A stimulated-echo sequence for detecting spin displacements. This sequence detects spin displacements along the Zt direction. TM is mixing time.

Fig. 4.4.7 (a) Reconstruction of the Stationary Helical Vortex (SHV) mode from MRI data acquired with the spin-tagging spin-echo sequence [27], The axial flow is upwards and the inner cylinder is rotating clockwise. The two helices represent the counter-rotating vortex streamtubes. (b) Construction of Poincare map for SHV [41]. The orbit of a typical particle is... 

All imaging experiments used the two-pulse spin-echo sequence a-T-2a-t-echo. In 3H experiments, a = 90 ° was used. For 2D 1H M RI of liquids, a 2-mm thick axial... 

Self-Diffusion of Desmopressin and Monoolein by NMR. The self-diffusion coefficient was measured with the NMR diffusion technique using a Bruker MSL 100 spectrometer. Two magnetic field gradient pulses were applied at either side of the 180-degree pulse in a [90x-T-180y-T-echo] spin echo sequence (7,8) (Figure 2). Due to diffusion, the amplitude of a component in the spin-echo spectrum is attenuated according to (7)... 

Both find their origin in the spin-echo sequence, devised hy Hahn in 1952 and used for the determination of relaxation times. 

Acquisition of wide static or MAS spectra of the CT is typically made using a two-pulse echo sequence nil t n (the Hahn echo [55,106]). By setting the strength of the rf-field at mrf = Aco/(I+ 1/2), where Aco is the CT linewidth, these sequences selectively irradiate the CT, while minimizing the contributions from the STs [107, 108]. In such case, the opjj frequencies are given by (29) ... 

Metais, A. and Mariette, F. 2003. Determination of water self-diffusion coefficient in complex food products by low field h-1 PFG-NMR Comparison between the standard spin-echo sequence and the T-l-weighted spin-echo sequence. J. Magn. Reson. 165, 265-275. 

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