Dispersion, vessels

If, for simplicity, it is assumed that the soluble impurity is in solution and that solution concentrations are constant throughout the dispersion vessel, then wash liquor requirements for decantation washing may be estimated as follows. 

Gas Dispersion—Vessel Headspace Boerma and Lankester have measured the surface aeration of a nine-bladed disk-type turbine (note A well-designed pitched-blade turbine will give equd or better performance). In a fully baffled vessel, the optimum depth to obtain maximum gas dispersion was 15 to 50 percent of the impeller diameter. 

The water—carbon slurry formed in the quench vessel is separated from the gas stream and flows to the carbon recovery system needed for environmental reasons and for better thermal efficiency. The recovered carbon is recycled to the reactor dispersed in the feedstock. If the fresh feed does not have too high an ash content, 100% of the carbon formed can be recycled to extinction. 

Wetox uses a single-reactor vessel that is baffled to simulate multiple stages. The design allows for higher destmction efficiency at lower power input and reduced temperature. Its commercial use has been limited to one faciHty in Canada for treatment of a complex industrial waste stream. Kenox Corp. (North York, Ontario, Canada) has developed a wet oxidation reactor design (28). The system operates at 4.1—4.7 MPa (600 to 680 psi) with air, using a static mixer to achieve good dispersion of Hquid and air bubbles. 

This correlation is valid when turbulent conditions exist in an agitated vessel, drop diameter is significantly bigger than the Kohnogoroff eddy length, and at low dispersed phase holdup. The most commonly reported correlation is based on the Weber number ... 

Eye. Adverse effects may be produced by splashes of Hquids or soflds, and by materials dispersed in the atmosphere. The eye is particularly sensitive to peripheral sensory irritants in the atmosphere. Toxic effects that may be induced include transient acute inflammation, persistent damage, and, occasionally, sensitivity reactions. ToxicologicaHy significant amounts of material may be absorbed by the periocular blood vessels in cases of splash contamination of the eye with materials of high acute toxicity (58). 

Carbonates. Basic zirconium carbonate [37356-18-6] is produced in a two-step process in which zirconium is precipitated as a basic sulfate from an oxychloride solution. The carbonate is formed by an exchange reaction between a water slurry of basic zirconium sulfate and sodium carbonate or ammonium carbonate at 80°C (203). The particulate product is easily filtered. Freshly precipitated zirconium hydroxide, dispersed in water under carbon dioxide in a pressure vessel at ca 200—300 kPa (2—3 atm), absorbs carbon dioxide to form the basic zirconium carbonate (204). Washed free of other anions, it can be dissolved in organic acids such as lactic, acetic, citric, oxaUc, and tartaric to form zirconium oxy salts of these acids. 

Sugar Processing. Dispersants are used in the production of cane and beet sugar to increase the time between evaporator clean outs. Typical scales encountered include calcium sulfate, calcium oxalate, calcium carbonate, and silica. Dispersants are fed at various points in the process to prevent scale buildup, which would interfere with efficient heating of the vessels. Only certain dispersants, conforming to food additive regulations, can be used, since a small amount of the dispersant may be adsorbed on the sugar crystals. 

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